Hibonite
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About Hibonite
Formula:
CaAl12O19
Ca may be replaced by minor Ce, Al by minor Ti and Mg.
Colour:
Black to brownisk black
Lustre:
Vitreous
Hardness:
7½ - 8
Specific Gravity:
3.83 - 3.85
Crystal System:
Hexagonal
Member of:
Name:
Named after Paul Hibon, a french prospector in Madagascar, who discovered the mineral in june 1953. He sent a parcel with some samples to Jean Behier for examination in the same year. Behier recognized it as a possible new mineral and gave it the working name "hibonite". He forwarded the sample to C. Guillemin, Labratoire de Minéralogie de la Sorbonne, in Paris, France to be further analyzed. It resulted in a description of the new mineral by Curien et al (1956).
Classification of Hibonite
Approved, 'Grandfathered' (first described prior to 1959)
4/C.08-30
4.CC.45
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
C : With large and medium-sized cations
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
C : With large and medium-sized cations
7.4.1.1
7 : MULTIPLE OXIDES
4 : AB12X19
7 : MULTIPLE OXIDES
4 : AB12X19
7.9.11
7 : Oxides and Hydroxides
9 : Oxides of Ti
7 : Oxides and Hydroxides
9 : Oxides of Ti
Pronounciation of Hibonite
Pronounciation:
Play | Recorded by | Country |
---|---|---|
Jolyon & Katya Ralph | United Kingdom |
Physical Properties of Hibonite
Vitreous
Transparency:
Opaque
Colour:
Black to brownisk black
Comment:
Reddish-brown and translucent in thin fragments
Streak:
Brown
Hardness:
7½ - 8 on Mohs scale
Cleavage:
Perfect
on {0001}
on {0001}
Parting:
on {10-10}
Fracture:
Sub-Conchoidal
Density:
3.83 - 3.85 g/cm3 (Measured)
Optical Data of Hibonite
Type:
Uniaxial (-)
RI values:
nω = 1.807 nε = 1.790 n = 1.807
Max Birefringence:
δ = 0.017

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Very High
Pleochroism:
Visible
Comments:
O brownish-gray, E gray.
Chemical Properties of Hibonite
Formula:
CaAl12O19
Ca may be replaced by minor Ce, Al by minor Ti and Mg.
Ca may be replaced by minor Ce, Al by minor Ti and Mg.
Elements listed:
Common Impurities:
Fe,Si
Chemical Analysis
Oxide wt%:
1 | |
---|---|
TiO2 | 0.5 % |
Al2O3 | 86.1 % |
V2O3 | 5.8 % |
MgO | 0.6 % |
CaO | 8.3 % |
Total: | 101.3 % |
Sample references:
ID | Locality | Reference | Notes |
---|---|---|---|
1 | Dellagiustaite type locality, Sierra de Comechingones, San Luis Province, Argentina | Frank K. Mazdab collection sample FKM-202 |
Crystallography of Hibonite
Crystal System:
Hexagonal
Cell Parameters:
a = 5.613(1) Å, c = 22.285(8) Å
Ratio:
a:c = 1 : 3.97
Unit Cell V:
608.04 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Hexagonal prismatic crystals, flattened on {0001}, also showing steep pyramids. The face {0001} is commonly divided into 6 sectors.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0005520 | Hibonite | Bermanec V, Holtstam D, Sturman D, Criddle A J, Back M E, Scavnicar S (1996) Nezilovite, a new member of the magnetoplumbite group, and the crystal chemistry of mognetoplumbite and hibonite The Canadian Mineralogist 34 1287-1297 | ![]() | 1996 | 0 | 293 |
CIF Raw Data - click here to close
Geological Environment
Geological Setting:
In metamorphosed limestone, pyroxenite, gneiss, and granulite of the amphibolite to granulite facies; alluvials
Type Occurrence of Hibonite
General Appearance of Type Material:
Small up to 4 cm large, black hexagonal prismatic crystals.
Geological Setting of Type Material:
Found in an alluvial deposit close to thorianite-bearing skarns
Other Language Names for Hibonite
Relationship of Hibonite to other Species
Member of:
Other Members of this group:
Barioferrite | BaFe3+12O19 | Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc |
Batiferrite | BaTi2Fe3+8Fe2+2O19 | Hex. |
Gorerite | CaAlFe3+11O19 | Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc |
Haggertyite | BaFe2+4Fe3+2Ti5MgO19 | Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc |
Hawthorneite | BaMgTi3Cr4Fe2+2Fe3+2O19 | Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc |
Hibonite-(Fe) | FeAl12O19 | Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc |
Magnetoplumbite | (Pb,Mn)(Fe,Mn)12O19 | Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc |
Nežilovite | PbZn2Mn4+2Fe3+8O19 | Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc |
Plumboferrite | Pb2(Fe3+,Mn2+,Mg)11O19 | Trig. 3 2 : P3 1 2 |
UM1994-07-O:BaCrFeMgTi | BaTi5Fe4Mg2CrO19 | |
UM1994-08-O:CaFeKMgTi | KTi5Fe3Cr2Mg2O19 | |
Unnamed (Mn-analogue of Plumboferrite) | Pb-Mn-O | |
Yimengite | K(Cr,Ti,Fe,Mg)12O19 | Hex. |
Common Associates
Associated Minerals Based on Photo Data:
Related Minerals - Nickel-Strunz Grouping
4.CC. | Allendeite | Sc4Zr3O12 | Trig. 3 : R3 |
4.CC. | Bitikleite | Ca3SbSn(AlO4)3 | Iso. m3m (4/m 3 2/m) : Ia3d |
4.CC. | Yttriaite-(Y) | Y2O3 | Iso. |
4.CC. | Anzaite-(Ce) | Ce3+ 4Fe2+Ti6O18 (OH)2 | Mon. 2/m : B2/m |
4.CC. | Botuobinskite | SrFe2+(Ti4+12Cr3+6)Mg2[O36(OH)2] | Trig. 3 : R3 |
4.CC.05 | Chrombismite | Bi3+16Cr6+O27 | Tet. |
4.CC.10 | Freudenbergite | Na2(Ti,Fe)8O16 | Mon. |
4.CC.15 | Grossite | CaAl4O7 | Mon. 2/m : B2/b |
4.CC.20 | Chlormayenite | Ca12Al14O32[◻4Cl2] | Iso. 4 3m : I4 3d |
4.CC.25 | Yafsoanite | Ca3Te6+2(ZnO4)3 | Iso. m3 (2/m 3) |
4.CC.30 | Latrappite | Ca2NbFe3+O6 | Orth. mmm (2/m 2/m 2/m) : Pnma |
4.CC.30 | Lueshite | NaNbO3 | Orth. mmm (2/m 2/m 2/m) |
4.CC.30 | Natroniobite | NaNbO3 | Mon. |
4.CC.30 | Perovskite | CaTiO3 | Orth. mmm (2/m 2/m 2/m) : Pnma |
4.CC.30 | Barioperovskite | BaTiO3 | Orth. mm2 : Amm2 |
4.CC.30 | Lakargiite | Ca(Zr,Sn,Ti)O3 | Orth. mmm (2/m 2/m 2/m) : Pnma |
4.CC.30 | Megawite | CaSnO3 | Orth. mmm (2/m 2/m 2/m) : Pban |
4.CC.35 | Loparite-(Ce) | (Na,REE)2Ti2O6 | Iso. m3m (4/m 3 2/m) |
4.CC.35 | Macedonite | PbTiO3 | Tet. 4/mmm (4/m 2/m 2/m) : P4/nmm |
4.CC.35 | Tausonite | SrTiO3 | Iso. 4 3m |
4.CC.35 | Isolueshite | (Na,La)NbO3 | Iso. m3m (4/m 3 2/m) : Pm3m |
4.CC.40 | Crichtonite | Sr(Mn,Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH)38 | Trig. 3 : R3 |
4.CC.40 | Davidite-(Ce) | Ce(Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH,F)38 | Trig. 3 : R3 |
4.CC.40 | Davidite-(La) | La(Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH,F)38 | Trig. |
4.CC.40 | Davidite-(Y) | (La,Ce,Na,Ca,Pb)(Y,Fe2+,◻)(Fe2+,Mn2+)2(Ti,Fe3+,Nb,Zr)18O38 (hypothetical) | Trig. |
4.CC.40 | Landauite | NaMnZn2(Ti,Fe)6Ti12O38 | Trig. 3 : R3 |
4.CC.40 | Lindsleyite | (Ba,Sr)(Zr,Ca)(Fe,Mg)2(Ti,Cr,Fe)18O38 | Trig. |
4.CC.40 | Loveringite | (Ca,Ce,La)(Zr,Fe)(Mg,Fe)2(Ti,Fe,Cr,Al)18O38 | Trig. |
4.CC.40 | Mathiasite | (K, Ba, Sr)(Zr, Fe)(Mg,Fe)2 (Ti,Cr,Fe)18O38 | Trig. |
4.CC.40 | Senaite | Pb(Mn,Y,U)(Fe,Zn)2(Ti,Fe,Cr,V)18(O,OH)38 | Trig. |
4.CC.40 | Dessauite-(Y) | (Sr,Pb)(Y,U)(Ti,Fe3+)20O38 | Trig. 3 : R3 |
4.CC.40 | Cleusonite | (Pb,Sr)(U4+,U6+)(Fe2+,Zn)2(Ti,Fe2+,Fe3+)18(O,OH)38 | Trig. 3 : R3 |
4.CC.40 | Gramaccioliite-(Y) | (Pb,Sr)(Y,Mn)Fe3+2(Ti,Fe3+)18O38 | Trig. 3 |
4.CC.45 | Diaoyudaoite | NaAl11O17 | Hex. |
4.CC.45 | Hawthorneite | BaMgTi3Cr4Fe2+2Fe3+2O19 | Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc |
4.CC.45 | Lindqvistite | Pb2Mn2+Fe16O27 | Hex. |
4.CC.45 | Magnetoplumbite | (Pb,Mn)(Fe,Mn)12O19 | Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc |
4.CC.45 | Plumboferrite | Pb2(Fe3+,Mn2+,Mg)11O19 | Trig. 3 2 : P3 1 2 |
4.CC.45 | Yimengite | K(Cr,Ti,Fe,Mg)12O19 | Hex. |
4.CC.45 | Haggertyite | BaFe2+4Fe3+2Ti5MgO19 | Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc |
4.CC.45 | Nežilovite | PbZn2Mn4+2Fe3+8O19 | Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc |
4.CC.45 | Batiferrite | BaTi2Fe3+8Fe2+2O19 | Hex. |
4.CC.45 | Hibonite-(Fe) | FeAl12O19 | Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc |
4.CC.45 | Barioferrite | BaFe3+12O19 | Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc |
4.CC.50 | Jeppeite | (K,Ba)2(Ti,Fe)6O13 | Mon. |
4.CC.55 | Zenzénite | Pb3Fe3+4Mn4+3O15 | Hex. |
4.CC.60 | Mengxianminite (of Huang et al.) | (Ca,Na)3(Fe,Mn)2Mg2(Sn,Zn)5Al8O29 |
Related Minerals - Dana Grouping (8th Ed.)
7.4.1.2 | Yimengite | K(Cr,Ti,Fe,Mg)12O19 | Hex. |
7.4.1.3 | Hawthorneite | BaMgTi3Cr4Fe2+2Fe3+2O19 | Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc |
Related Minerals - Hey's Chemical Index of Minerals Grouping
7.9.1 | Hongquiite | TiO | |
7.9.2 | Rutile | TiO2 | Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm |
7.9.3 | Anatase | TiO2 | Tet. 4/mmm (4/m 2/m 2/m) : I41/amd |
7.9.4 | Brookite | TiO2 | Orth. mmm (2/m 2/m 2/m) |
7.9.5 | Geikielite | MgTiO3 | Trig. 3 : R3 |
7.9.6 | Perovskite | CaTiO3 | Orth. mmm (2/m 2/m 2/m) : Pnma |
7.9.7 | Kassite | CaTi2O4(OH)2 | Orth. |
7.9.8 | Tausonite | SrTiO3 | Iso. 4 3m |
7.9.9 | Crichtonite | Sr(Mn,Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH)38 | Trig. 3 : R3 |
7.9.10 | Lucasite-(Ce) | CeTi2(O,OH)6 | Mon. |
7.9.12 | Yttrocrasite-(Y) | (Y,Th,Ca,U)(Ti,Fe)2(O,OH)6 | Amor. |
7.9.13 | Pyrophanite | Mn2+TiO3 | Trig. 3 : R3 |
7.9.14 | Jacobsite-Q | Mn2+(Fe3+,Mn3+)2O4 | Tet. 4/mmm (4/m 2/m 2/m) : I41/amd |
7.9.15 | Ilmenite | Fe2+TiO3 | Trig. 3 : R3 |
7.9.16 | Pseudobrookite | Fe2TiO5 | Orth. mmm (2/m 2/m 2/m) |
7.9.17 | Ulvöspinel | TiFe2O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
7.9.18 | Pseudorutile | Fe2Ti3O9 | Hex. |
7.9.19 | Freudenbergite | Na2(Ti,Fe)8O16 | Mon. |
7.9.20 | Kennedyite | (Fe,Mg)2TiO5 | |
7.9.21 | Armalcolite | (Mg,Fe2+)Ti2O5 | Orth. mmm (2/m 2/m 2/m) |
7.9.22 | Högbomite | (Mg,Fe)2(Al,Ti)5O10 | Hex. |
7.9.23 | Qandilite | (Mg,Fe3+)2(Ti,Fe3+,Al)O4 | Iso. m3m (4/m 3 2/m) : Fd3m |
7.9.24 | Cafetite | CaTi2O5 · H2O | Mon. 2/m : P21/b |
7.9.25 | Loveringite | (Ca,Ce,La)(Zr,Fe)(Mg,Fe)2(Ti,Fe,Cr,Al)18O38 | Trig. |
7.9.26 | Lindsleyite | (Ba,Sr)(Zr,Ca)(Fe,Mg)2(Ti,Cr,Fe)18O38 | Trig. |
7.9.27 | Priderite | K(Ti4+7Fe3+)O16 | Tet. |
7.9.28 | Jeppeite | (K,Ba)2(Ti,Fe)6O13 | Mon. |
7.9.29 | Ankangite | Ba(Ti,V3+,Cr)8O16 | Tet. 4/m : I4/m |
7.9.30 | Ecandrewsite | (Zn,Fe2+,Mn2+)TiO3 | Trig. 3 : R3 |
7.9.31 | Landauite | NaMnZn2(Ti,Fe)6Ti12O38 | Trig. 3 : R3 |
Other Information
Notes:
Shows a very weak radioactivity: Th: 1000 p. p. m. U: 100 p. p. m. Disolves very slowly in a mixture of sulphuric and phosphoric acids.
en U.
en U.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
References for Hibonite
Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Delbos, L. (1955) Note sur le gisement d'un mineral nouveau "la hibonite" de' l'Androy Mandrareen. Rapport Annuel du Service Geologique pour 1955, Tananarivo: 143-144.
Curien, H., Guillemin, C., Orcel, J., Sternberg, M. (1956) La hibonite, nouvelle espèce minérale. Comptes Rendus Hebdomadaires des Séances de l’Académie des Sciences: 242: 2845-2847.
Behier, J. (1960) Contribution á la mineralogie de Madagascar. Annales Géologiques de Madagascar: 29: Tananarive: 73.
Fleischer, M. (1957) New mineral names. American Mineralogist: 42: 117-124.
Beckett, J.R., Live, D., Tsay, F.D., Grossman, L., Stolper, E. (1988) Ti3+ in meteoritic and synthetic hibonite. Geochimica et Cosmochimica Acta: 52: 1479-1495.
Bermanec, V., Holtstam, D., Sturman, D., Criddle, A.J., Back, M.E., Scavnicar, S. (1996) Nezilovite, a new member of the magnetoplumbite group, and the crystal chemistry of magnetoplumbite and hibonite. The Canadian Mineralogist: 34: 1287-1297.
Rakotondrazafy, M.A.F., Moine, B., Cuney, M. (1996) Mode of formation of hibonite (CaAl12O19) within the U-Th skarns from the granulites of S-E Madagascar. Contributions to Mineralogy and Petrology: 123: 190-201.
Utsunomiya, A., Tanaka, K., Morikawa, H., Marumo, F., Kojima, H. (1988) Structure refinement of CaO·6Al2O3. Journal of Solid State Chemistry: 75: 197-200.
Bermanec, V., Holtstam, D., Sturman, D., Criddle, A.J., Back, M.E., Scavnicar, S. (1996) Nezilovite, a new member of the magnetoplumbite group, and the crystal chemistry of magnetoplumbite and hibonite. The Canadian Mineralogist: 34: 1287-1297.
Ulianov, A., Kalt, A., Pettke, T. (2005) Hibonite, Ca(Al,Cr,Ti,Si,Mg,Fe2+)12O19, in granulite xenoliths from the Chyulu Hills volcanic field, Kenya. European Journal of Mineralogy: 17(2): 343-356.
Nagashaima, M., Armbruster, T., Hainschwang, T. (2010) A temperature-dependent structure study of gem-quality hibonite from Myanmar. Mineralogical Magazine: 74: 871-885.
Pankin, I.A., Kravtsova, A.N., Polozhentsev, O.E., Soldatov, A.V. (2016) Modelling of substitutional defects in the structure of Ti-bearing hibonite. Journal of Structural Chemistry: 57: 1369–1376.
Doyle, P.M., Schofield, P.F., Berry, A.J., Walker, A.M., Knight, K.S. (2014) Substitution of Ti3+ and Ti4+ in hibonite (CaAl12O19). American Mineralogist: 99: 1369-1382.
Giannini, M., Ballaran, T.B., Langenhorst, F. (2014) Crystal chemistry of synthetic Ti-Mg-bearing hibonites: a single-crystal X-ray study. American Mineralogist: 99: 2060-2067.
Miyawaki, R., Hatert, F., Pasero, M., Mills, S.J. (2019) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) Newsletter 50. New minerals and nomenclature modifications approved in 2019. Mineralogical Magazine: 83: 615-620.
Internet Links for Hibonite
mindat.org URL:
https://www.mindat.org/min-1897.html
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Localities for Hibonite
Locality List




All localities listed without proper references should be considered as questionable.
Algeria | |
| Lee, M.R., Russell, S.S., Arden, J.W., & Pillinger, C.T. (1995) Nierite (Si3N4), a new mineral from ordinary and enstatite chondrites. Meteoritics 30 (4): 387-397. (July 1995). |
| Weber D, Bischoff A (1994) Grossite (CaAl4O7) - a rare phase in terrestrial rocks and meteorites, European Journal of Mineralogy 6, 591-594 ; Weber, D., & Bischoff, A. (1992, March). Mineralogy and chemistry of refractory inclusions in CR-like chondrites from the Sahara desert. In Lunar and Planetary Institute Science Conference Abstracts (Vol. 23, p. 1505). |
| Weber, D. (1995). Refractory Inclusions From the Carbonaceous Chondrite Acfer 094 (Abstract). Meteoritics 30 (5), 595-596. (Sept 1995).; Anorthite, Augite, Corundum, Diopside, Forsterite, Grossite, Hibonite, Melilite, Olivine, Perovskite, Pigeonite, Plagioclase, Pyroxene, Spinel ; Krot, A. N., Fagan, T. J., Keil, K., McKeegan, K. D., Sahijpal, S., Hutcheon, I. D., Petaev, M. I. & Yurimoto, H. (2004). Ca,Al-rich inclusions, amoeboid olivine aggregates, and Al-rich chondrules from the unique carbonaceous chondrite Acfer 094: I. mineralogy and petrology. Geochimica et Cosmochimica Acta 68 (9), 2167-2184. (May 2004). |
Weber D, Bischoff A (1994) Grossite (CaAl4O7) - a rare phase in terrestrial rocks and meteorites, European Journal of Mineralogy 6, 591-594 | |
Ma, C., Krot, A.N., Nagashima, K. (2017): Addibischoffite, Ca2Al6Al6O20, a new calcium aluminate mineral from the Acfer 214 CH carbonaceous chondrite: A new refractory phase from the solar nebula. American Mineralogist: 102: 1556-1560. | |
Angola | |
| Beleque, A. R. C. (2010). Minerais de ETR no complexo carbonatítico de Bailundo (Mungo, Angola): ocorrência, composição e significado económico. |
Antarctica | |
| Brearley, A. J. & Jones, R. H. (1998) Chondritic Meteorites: IN: Planetary Materials (Papike, J.J. [Ed.]), Chapter 3, 398 pages: Mineralogical Society of America: Washington, DC, USA. |
| Jeffrey N. Grossman, Alan E. Rubin & Glenn J. MacPherson (1988). Allan Hills 85085: an Out-of-the-Ordinary, Enstatite-rich Carbonaceous Chondrite. Abstracts of the Lunar and Planetary Science Conference, vol. 19, p. 433. |
Russell, S. S., Greenwood, R. C., Fahey, A. J., Huss, G. R., & Wasserburg, G. J. (1994) An ion microprobe study of CAIs from CO3 meteorites: Meteoritics 29 (4): 525-526. (July 1994). | |
Needham, A. W. & Messenger, S. (2103) Corundum-Hibonite Inclusions and the Environments of High Temperature Processing in the Early Solar System: Lunar and Planetary Science Conference XLIV. LPI Contribution No. 1719, p.2929. (March 2013) | |
Argentina | |
| J. D. MacDougall & J. Carlson (1978). Refractory Element Rich Inclusions in c1 and c2 Meteorites (Abstract). Lunar and Planetary Science IX, pp. 683-685. |
| Cámara, F., Bindi, L., Pagano, A., Pagano, R., Gain, S.E.M., Griffin, W.L. (2019): Dellagiustaite: A Novel Natural Spinel Containing V2+. Minerals, 9, 4; |
Anthony Kampf, John Attard and Gunnar Färber analyses; additional analyses by Frank K. Mazdab, University of Arizona | |
Australia | |
| Russell, S.S., Huss, G.R., MacPherson, G.J. & Wasserburg, G.J. (1997) Early and late chondrule formation - New constraints for solar nebula chronology from Al-26/Al-27 in unequilibrated ordinary chondrites: 28th Annual Lunar and Planetary Science Conference: 209-210. |
| Hutcheon, I. D. & Steele, I. M. (1982) Refractory Inclusions in the Adelaide Carbonaceous Chondrite (Abstract): Lunar and Planetary Science XIII: 352-353. (March 1982) |
| Louis H. Fuchs, Kenneth J. Jensen & Edward Olsen (1970). Mineralogy and Composition of the Murchison Meteorite. Meteoritics 5, #4, p. 198. (Dec 1970). |
Azerbaijan | |
| Brearley, A. J. & Jones, R. H. (1998): Chondritic Meteorites. In: Planetary Materials (Papike, J. J., Editor): Chapter 3, 398 pages. Mineralogical Society of America: Washington, DC, USA. (1998) ; Lee M R, Russell S S, Arden J W, Pillinger C T (1995) Nierite (Si3N4), a new mineral from ordinary and enstatite chondrites, Meteoritics, 30, 387-398 |
Belgium | |
| Analysed at Université du Maine, Laboratoire de Fluorures. Le Mans, France |
Canada | |
| Meteoritics & Planetary Sci. 38 (May 2003) |
China | |
| Zheng-Min Cao, Shan Qin, Yu-Run Bi, and Jian-Wei Wang (1997): Acta Petrologica et Mineralogica [Yanshikuangwuxue Zazhi] 16(4), 353-356. |
| Wang, Y. & Hsu, W. (2009). Petrology and Mineralogy of the Ningqiang carbonaceous chondrite. Meteoritics & Planetary Science Vol. 44, #5, 763-780. (May 2009). |
Czech Republic | |
| Lee M R, Russell S S, Arden J W, Pillinger C T (1995) Nierite (Si3N4), a new mineral from ordinary and enstatite chondrites, Meteoritics, 30, 387-398; Lee, M.R., Russell, S.S., Arden, J.W., & Pillinger, C.T. (1995) Nierite (Si3N4), a new mineral from ordinary and enstatite chondrites. Meteoritics 30 (4): 387-397. (July 1995). ; Krestina, N., Hsu, W., Wasserburg, G.J. (2002) Circumstellar oxide grains in ordinary chondrites and their origin (abstract). Lunar Planet. Sci. 33: pdf.1425. |
Denmark | |
| Haack H. et al. (2012). Maribo—A New CM fall from Denmark. Meteoritics & Planetary Science 47(1): 30-50. (Jan 2012). |
DR Congo | |
| El Goresy et al. (1984) A calcium-aluminum-rich inclusion from the Essebi (CM2) chondrite: Evidence for captured spinel-hibonite spherules and for an ultra-refractory rimming sequence. Geochimica et Cosmochimica Acta 48 (11): 2283–2298. (Nov 1984) |
Egypt | |
| Russell, S. S., Greenwood, R. C., Fahey, A. J., Huss, G. R. & Wasserburg, G. J. (1994). An ion microprobe study of CAIs from CO3 meteorites. Meteoritics 29 (4): 525-526. (Jul 1994) |
France | |
| A. M. Davis (1985). Refractory Inclusions in the Ornans C3O Chondrite (Abstract). Lunar and Planetary Science XVI, pp. 165-166. |
| Brearley, A. J. & Jones, R. H. (1998): Chondritic Meteorites. In: Planetary Materials (Papike, J. J., Editor): Chapter 3, 398 pages. Mineralogical Society of America: Washington, DC, USA. (1998) |
| Marrocchi, Y., Gounelle, M., Blanchard, I., Caste, F. & Kearsley, A.T. (2014) The Paris CM chondrite: secondary minerals and asteroidal processing. Meteoritics & Planetary Science: 49 (7): 12321249. (July 2014).; Hewins, Roger H. & 16 others (2014) The Paris meteorite, the least altered CM chondrite so far. Geochimica et Cosmochimica Acta 124: 190-222. (1 January 2014); Rubin, A. E. (2015) An American on Paris: Extent of aqueous alteration of a CM chondrite and the petrography of its refractory and amoeboid olivine inclusions. Meteoritics & Planetary Science 50(9): 1595-1612. (Sept 2015). |
| Ian D. Hutcheon, Gary R. Huss, Albert J. Fahey & Gerald J. Wasserburg (1994). Extreme Mg-26 and O-17 enrichments in an Orgueil corundum: Identification of a presolar oxide grain. Astrophysical Journal, Part 2 - Letters, vol. 425, # 2, p. L97-L100. |
India | |
| Brearley, A.J. & Jones, R.H. (1998) Chondritic Meteorites. In: Planetary Materials (Papike, JJ - Ed.), Chapter 3: 1-398: Mineralogical Society of America, Washington, DC, USA. |
| Rajesh, V. J., Arai, S., Santosh, M., & Tamura, A. (2010). LREE-rich hibonite in ultrapotassic rocks in southern India. Lithos, 115(1-4), 40-50. Sandiford, M., & Santosh, M. (1991). A granulite facies kalsilite-leucite-hibonite association from Punalur, Southern India. Mineralogy and Petrology, 43(3), 225-236. Rajesh, V. J., Arima, M., & Santosh, M. (2004). Dunite, glimmerite and spinellite in Achankovil Shear Zone, South India: implications for highly potassic CO2-rich melt influx along an intra-continental shear zone. Gondwana Research, 7(4), 961-974. Rajesh, V. J., & Arai, S. (2006). Baddeleyite-apatite-spinel-phlogopite (BASP) rock in Achankovil Shear Zone, South India, as a probable cumulate from melts of carbonatite affinity. Lithos, 90(1-2), 1-18. |
| Brearley, A. J. & Jones, R. H. (1998). Chondritic Meteorites. In: Planetary Materials (Papike, J. J., Editor): Chapter 3, 398 pages. Mineralogical Society of America: Washington, DC, USA. (1998) ; Srinivasan, G., Russell, S.S., MacPherson, G.J., Huss, G.R. & Wasserburg, G. J. (1996) New Evidence for 26Al in CAI and Chondrules from Type 3 Ordinary Chondrites: Lunar and Planetary Science 27: 1257-1258.; Russell, S.S., Huss, G.R., MacPherson, G.J. & Wasserburg, G.J. (1997) Early and late chondrule formation - New constraints for solar nebula chronology from Al-26/Al-27 in unequilibrated ordinary chondrites: 28th Annual Lunar and Planetary Science Conference: 209-210. |
| Prinz, M., Weisberg, M. K., Nehru, C. E., MacPherson, G. J., Clayton, R. N. & Mayeda, T. K. (1989) Petrologic and Stable Isotope Study of the Kakangari (K-Group) Chondrite: Chondrules, Matrix, CAI's, Abstracts of the Lunar and Planetary Science Conference XX, page 870. (March 1989) ; Grady, M. M., Pratesi, G. & Moggi-Cecchi, V. (2015) Atlas of Meteorites. Cambridge University Press: Cambridge, United Kingdom. 373 pages. |
| Krestina, N., Hsu, W., Wasserburg, G.J. (2002) Circumstellar oxide grains in ordinary chondrites and their origin (abstract). Lunar Planet. Sci. 33: pdf.1425. |
Israel | |
| J. Hattingh (2019) Updated Competent Person’s Report on the Shefa Gems Ltd Gemstone Assets. |
| Griffin, W. L., Gain, S. E. M., Adams, D. T., Huang, J. X., Saunders, M., Toledo, V., ... & O’Reilly, S. Y. (2016). First terrestrial occurrence of tistarite (Ti2O3): Ultra-low oxygen fugacity in the upper mantle beneath Mount Carmel, Israel. Geology, 44(10), 815-818.; Griffin, W.L., Gain, S.E.M., Huang, J.-X., Saunders, M., Shaw, J., Toledo, V., O’Reilly, S.Y. (2018): A terrestrial magmatic hibonite-grossite-vanadium assemblage: desilication and extreme reduction in a volcanic plumbing system, Mt Carmel, Israel. American Mineralogist, 103, (in press).; Cámara, F., Bindi, L., Pagano, A., Pagano, R., Gain, S.E.M., Griffin, W.L. (2019): Dellagiustaite: A Novel Natural Spinel Containing V2+. Minerals, 9, 4; https://doi.org/10.3390/min9010004 |
Italy | |
| Weisberg, M. K. , Prinz, M., Clayton, R. N. , and Mayeda, T.K. (1989) The Renazzo-type CR chondrites. Meteoritics, 24, 339 (abstract). |
| Christophe-Michel-Levy, M., Caye, R., and Nelen, J. (1970) A new mineral in the Vigarano meteorite. Meteoritics, 5, 211; Mao, X.-Y., Ward, B.J., Grossman, L., and MacPherson, G.J. (1990) Chemical compositions of refractory inclusions from the Vigarano and Leoville carbonaceous chondrites. Geochimica et Cosmochimica Acta, 54, 7, 2121-2132. |
Kazakhstan | |
| Lunar and Planetary Science XXXI |
Kenya | |
| Rout, S. S. & Bischoff, A. (2008) Ca,Al-rich Inclusions in Rumuruti Chondrites: Lunar and Planetary Science XXXIX. LPI Contribution No. 1391: p.1255. (March 2008) |
| Ulianov, A., Kalt, A., Pettke, T. (2005) Hibonite, Ca (Al, Cr, Ti, Si, Mg, Fe2+)12 O19, in granulite xenoliths from the Chyulu Hills volcanic field, Kenya. European Journal of Mineralogy, 17:2, 343-356. |
Madagascar | |
| Behier, J. (1963): Carte mineralogique de Madagascar. Archive Service Géologique Madagascar. A 1871 |
Behier, J. (1963): Carte mineralogique de Madagascar. Archive Service Géologique Madagascar. A 1871 | |
Giuliani, G., Fallick, A., Rakotondrazafy, M., Ohnenstetter, D., Andriamamonjy, A., Ralantoarison, T., Rakotosamizanany, S., Razanatseheno, M., Offant, Y., Garnier, V., Dunaigre, C., Schwarz, D., Mercier, A., Ratrimo, V., and Ralison, B. (2007): Mineralium Deposita 42, 251-270. | |
Rakotondrazafy, M.A.F., Moine, B. and Cuney, M. (1996) Mode of formation of hibonite (CaAl12O19) within the U-Th skarns from the granulites of S-E Madagascar. Contributions to Mineralogy and Petrology: 123: 190-201 | |
Arliguie M. photo and specimen | |
Behier, J. (1960): Contribution á la Minéralogie de Madagascar. Annales Géologiques de Madagascar XXIX, Tananarive, p 42; Rakotondrazafy, M.A.F., Moine, B. and Cuney, M. (1996) Mode of formation of hibonite (CaAl12O19) within the U-Th skarns from the granulites of S-E Madagascar. Contributions to Mineralogy and Petrology: 123: 190-201 | |
| Delbos, L. (1955): Note sur le gisement d'un mineral nouveau " la hibonite" de' l'Androy Mandrareen" in Rapport Annuel du Service Geologique pour 1955, Tananarivo.143-144 |
Rakotondrazafy, M.A.F., Moine, B. and Cuney, M. (1996) Mode of formation of hibonite (CaAl12O19) within the U-Th skarns from the granulites of S-E Madagascar. Contributions to Mineralogy and Petrology: 123: 190-201 | |
| Delbos, L. (1955): Note sur le gisement d'un mineral nouveau " la hibonite" de' l'Androy Mandrareen" in Rapport Annuel du Service Geologique pour 1955, Tananarivo.143-144; Behier, J. (1963): Carte mineralogique de Madagascar. Archive Service Géologique Madagascar. A 1871 |
Rakotondrazafy, M.A.F., Moine, B. and Cuney, M. (1996) Mode of formation of hibonite (CaAl12O19) within the U-Th skarns from the granulites of S-E Madagascar. Contributions to Mineralogy and Petrology: 123: 190-201 | |
Delbos, L. (1955): Note sur le gisement d'un mineral nouveau " la hibonite" de' l'Androy Mandrareen" in Rapport Annuel du Service Geologique pour 1955, Tananarivo, 143-144 | |
Knut Edvard Larsen collection # M-61; Rakotondrazafy, M.A.F.,Moine,B. & Cuney , M. (1996): Mode of formation of hibonite (CaAl12O19) within the U-Th skarns from the granulites of S-E Madagascar. Contributions to Mineralogy and Petrology. 123 (2), 190-201 | |
Schwab, P-N. (1997): Informations Minéralogiques, Géologiques et Paléontologiques. Munich 1997-21-22-23 novembre 1997. La Mecque annuelle de la minéralogie européene. La Règne Minéral 19, 49-54 [A short note one a find of hibonite at Andrakaholo p. 52] | |
Rakotondrazafy, M.A.F., Moine, B. and Cuney, M. (1996) Mode of formation of hibonite (CaAl12O19) within the U-Th skarns from the granulites of S-E Madagascar. Contributions to Mineralogy and Petrology: 123: 190-201 | |
Knut Edvard Larsen info | |
Delbos, L. (1955): Note sur le gisement d'un mineral nouveau " la hibonite" de' l'Androy Mandrareen" in Rapport Annuel du Service Geologique pour 1955, Tananarivo.143-144 | |
Mexico | |
| American Mineralogist, Volume 94, pages 1483–1486, 2009; Ma, C., Paque, J., & Tschauner, O. (2016, March). Discovery of Beckettite, Ca2V6Al6O20, a New Alteration Mineral in a V-Rich Ca-Al-Rich Inclusion from Allende. In Lunar and Planetary Science Conference (Vol. 47, p. 1704). |
Middle East | |
Gross, S. (1977): The Mineralogy of the Hatrurim Formation, Israel. Geological Survey of Israel, Bulletin no. 70, 80 pp. | |
Morocco | |
| Ivanova, M. A. et al (2002): Meteorit.Planet. Sci. 37, 1337-1444. |
Myanmar | M. Nagashaima1, T. Armbruster1 and T. Hainschwang (2010): A temperature-dependent structure study of gem-quality hibonite from Myanmar. Mineralogical Magazine 74, 871-885. [p. 874: "probably from Mogok"] |
| Harald Schillhammer collection |
Wild, M. & Milisenda, C.C. (2013): Hibonit aus Myanmar (Burma). Z. Dt. Gemmolog. Ges. 62/1-2, 25-30 (in German).; Sieghard Ellenberger data | |
Northwest Africa Meteorites | |
Stuart A. Sweeney Smith (2010) Characterization of two atypical refractory inclusions from separate CV3 chondritic meteorites: Petrogenesis in the early Solar System . Senior Comprehensive Exercise Carleton College, Northfield, Minnesota. | |
Norway | |
| Dahlgren, S. (2005): Miljøgeologisk undersøkelse av lavradioaktivt slagg fra ferroniobproduksjonen ved Norsk Bergverk på Søve 1956-1965. Regiongeologen for Buskerud, Telemark og Vestfold, Rapport nt 1, 2005. 19-28. |
Oman | |
| Zhang, A., & Hsu, W. (2009). Refractory inclusions and aluminum‐rich chondrules in Sayh al Uhaymir 290 CH chondrite: Petrography and mineralogy. Meteoritics & Planetary Science, 44(6), 787-804. |
Romania | |
| Michel‐Lévy, M. C. (1988). A New Component of the Mezö‐Madaras Breccia: A Microchondrule‐and Carbon‐Bearing L‐Related Chondrite. Meteoritics, 23(1), 45-48. |
Russia | |
| Krot, A. N., Ulyanov, A. A. & Ivanova, M. A. (2008) Refractory inclusions in the CH/CB-like carbonaceous chondrite Isheyevo: I. Mineralogy and petrography. Meteoritics & Planetary Science 43, #9, 1531-1550. (Sept 2008) |
| Pavel M. Kartashov data; Коноваленко, С. И., Konovalenko, S. I., Ананьев, С. А., Ananyev, S. A., Гармаева, С. С., & Garmayeva, S. S. (2012). Редкие и новые минералы ташелгино-майзаской зоны Горной Шории, их особенности и природа. |
| Pavel M. Kartashov data |
| T. Ushikubo, H. Hiyagon & Naogi Sugiura (2000). A FUN-like Hibonite Inclusion in Kainsaz CO3 Chondrite with Large 41K and 26Mg Excesses at the Level of Normal CAIs. 31st Annual Lunar and Planetary Science Conference, March 13-17, 2000, Houston, Texas, abstract #1561. |
South Africa | |
| Richard C. Greenwood, Robert Hutchinson & G. Cressy (1991). Spinel-bearing refractory inclusions in Cold Bokkeveld. Meteoritics 26, #4, 340. (Dec 1991). |
Tanzania | |
| Maaskant, P., Coolen, J. J. M., & Burke, E. A. J. (1980). Hibonite and coexisting zoisite and clinozoisite in a calc-silicate granulite from southern Tanzania. Mineralogical Magazine, 43(332), 995-1003. |
Ukraine | |
| Nittler, L.R., C.M.O'D. Alexander, F.J. Stadermann, and E.K. Zinner (____) Presolar Al-, Ca-, and Ti-rich Oxide Grains in the Krymka Meteorite.; Semenenko, V.P., Bischoff, A., Weber, I., Perron, C. & Girich, A.L. (2001). Mineralogy of fine-grained material in the Krymka (LL3) chondrite: Meteoritics & Planetary Science 36(8): 1067-1085. (Aug 2001). |
MacPherson, G. J. (1984). Refractory inclusions in the Mighei C2 meteorite. Abstracts and Program for the 47th Annual Meeting of the Meteoritical Society, Co-sponsored by the University of New Mexico and the Lunar and Planetary Institute LPI Contribution 537, p. 50. | |
USA | |
| Kracher, A., Keil, K., Kallemeyn, G. W., Wasson, J. T., Clayton, R. N. & Huss, G. I. (1985). The Leoville (CV3) accretionary breccia. Journal of Geophysical Research, Supplement, vol. 90: p. D123-D135. (Nov 1985) |
| Lee M R, Russell S S, Arden J W, Pillinger C T (1995) Nierite (Si3N4), a new mineral from ordinary and enstatite chondrites, Meteoritics, 30, 387-398 |
| American Mineralogist, Volume 94, pages 1483–1486, 2009; Phinney, D., MacDougall, J. D., & Whitehead, B. (1979). Magnesium Isotopes in Hibonite-Bearing Inclusions from CM Meteorites (Abstract). LUNAR AND PLANETARY SCIENCE X, P. 975-977. |
| Greenwood, R. C., Hutchison, R., Huss, G. R. & Hutcheon, I. D. (1992) CAIs in CO3 Meteorites: Parent Body or Nebular Alteration? Meteoritics 27 (3): 229. (July 1992) |
| Rubin, A. E., James, J. A., Keck, B. D., Weeks, K. S., Sears, D. W. G. & Jarosewich, E. (1985) The Colony meteorite and variations in CO3 chondrite properties. Meteoritics 20(2, part 1): 175-196. (June 1985); Grossite, Hibonite, Melilite |
| Srinivasan, G., Huss, G. R. & Wasserburg, G. J. ( 2000). A petrographic, chemical, and isotopic study of calcium-aluminum-rich inclusions and aluminum-rich chondrules from the Axtell (CV3) chondrite. Meteoritics & Planetary Science 35 (6): 1333-1354. (Nov 2000) |
| Mineralogical Magazine 1998 62 : 265-269 |
| Brearley, A.J. & Jones, R.H. (1998) Chondritic Meteorites. In: Planetary Materials (Papike, JJ - Ed.), Chapter 3: 1-398: Mineralogical Society of America, Washington, DC, USA. ; Bischoff, A. & Keil, K. (1984) Al-rich objects in ordinary chondrites: Related origin of carbonaceous and ordinary chondrites and their constituents. Geochimica et Cosmochimica Acta 48 (4): 693-709. |
Yemen | |
| Zolensky, M. & A.Ivanov, Chemie der Erde 63,185-246(2003) |
Outer Space | European Journal of Mineralogy; December; v. 19; no. 6; p. 771-782; DOI: 10.1127/0935-1221/2007/0019-1766 |
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Vohimena deposit, Tranomaro, Amboasary Sud, Anosy, Madagascar