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Griphite

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About GriphiteHide

Formula:
Na4Li2Ca6(Mn2+,Fe2+,Mg)19Al8(PO4)24(F,OH)8
Colour:
Yellow, dark-brown, brownish-black; yellowish brown to brown in transmitted light.
Lustre:
Vitreous, Resinous
Hardness:
Specific Gravity:
3.4
Crystal System:
Isometric
Name:
From the Greek γρίφος for "puzzle," in allusion to the chemical composition.
This page provides mineralogical data about Griphite.


Classification of GriphiteHide

Approved, 'Grandfathered' (first described prior to 1959)
8.BF.15

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
F : With medium-sized and large cations, (OH, etc.):RO4< 0.5:1
41.9.3.1

41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
9 : (AB)5(XO4)3Zq
19.12.51

19 : Phosphates
12 : Phosphates of Mn

Physical Properties of GriphiteHide

Vitreous, Resinous
Transparency:
Translucent
Colour:
Yellow, dark-brown, brownish-black; yellowish brown to brown in transmitted light.
Hardness:
5½ on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Irregular/Uneven, Conchoidal
Density:
3.4 g/cm3 (Measured)    3.4 g/cm3 (Calculated)

Optical Data of GriphiteHide

Type:
Isotropic

Chemical Properties of GriphiteHide

Formula:
Na4Li2Ca6(Mn2+,Fe2+,Mg)19Al8(PO4)24(F,OH)8
IMA Formula:
Ca(Mn2+,Na,Li)6Fe2+Al2(PO4)6(F,OH)2

Crystallography of GriphiteHide

Crystal System:
Isometric
Class (H-M):
m3 (2/m 3) - Diploidal
Space Group:
Pa3
Setting:
Pa3
Cell Parameters:
a = 12.22 Å
Unit Cell V:
1,824.79 ų (Calculated from Unit Cell)
Morphology:
Massive; reniform at times.

X-Ray Powder DiffractionHide

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Radiation - Copper Kα
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.

Type Occurrence of GriphiteHide

Other Language Names for GriphiteHide

German:Griphit
Russian:Грифит
Spanish:Griphita

Related Minerals - Nickel-Strunz GroupingHide

8.BF.05Arrojadite-(KFe){KNa}{Fe2+◻}{Ca}{Na2◻}{Fe2+13}{Al}(PO4)11(HPO4)(OH)2Mon.
8.BF.05Dickinsonite-(KMnNa){KNa}{Mn2+◻}{Ca}{Na3}{Mn2+13}{Al}(PO4)12(OH)2Mon. 2/m : B2/b
8.BF.05Arrojadite-(BaFe){Ba◻}{Fe2+◻}{Ca}{Na2◻}{Fe2+13}{Al}(PO4)11(HPO4)(OH)2Mon.
8.BF.05Arrojadite-(SrFe){Sr◻}{Fe2+◻}{Ca}{Na2◻}{Fe2+13}{Al}(PO4)11(HPO4)(OH)2Mon. m : Bb
8.BF.05Arrojadite-(KNa){KNa}{Na2}{Ca}{Na2◻}{Fe2+13}{Al}(PO4)11(HPO4)(OH)2Mon. m : Bb
8.BF.05Arrojadite-(PbFe){Pb◻}{Fe2+◻}{Ca}{Na2◻}{Fe2+13}{Al}(PO4)11(HPO4)(OH)2Mon. m : Bb
8.BF.05Fluorarrojadite-(BaFe){Ba◻}{Fe2+◻}{Ca}{Na2◻}{Fe2+13}{Al}(PO4)11(HPO4)F2Mon. m : Bb
8.BF.05Arrojadite-(NaFe){Na2}{Fe2+◻}{Ca}{Na2◻}{Fe2+13}{Al}(PO4)11(HPO4)(OH)2
8.BF.05Arrojadite-(BaNa)BaNa3(NaCa)Fe2+13Al(PO4)11(PO3OH)(OH)Mon. 2/m : B2/b
8.BF.05Fluorarrojadite-(KNa){KNa}{Na2}{Ca}{Na2◻}{Fe2+13}{Al}(PO4)11(HPO4)F2
8.BF.05Fluorarrojadite-(NaFe){Na2}{Fe2+◻}{Ca}{Na2◻}{Fe2+13}{Al}(PO4)11(HPO4)F2
8.BF.10Samuelsonite(Ca,Ba)Ca8Fe2+2Mn2+2Al2(PO4)10(OH)2Mon. 2/m : B2/m
8.BF.20NabiasiteBaMn2+9(VO4,AsO4)6(OH)2Iso. m3 (2/m 3) : Pa3

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

19.12.1MetaswitzeriteMn2+3(PO4)2 · 4H2OMon. 2/m : P2/b
19.12.2BermaniteMn2+Mn3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P2/b
19.12.3NatrophiliteNaMn2+PO4Orth. mmm (2/m 2/m 2/m) : Pmna
19.12.4SidorenkiteNa3Mn2+(CO3)(PO4)Mon.
19.12.5Niahite(NH4)(Mn2+,Mg)(PO4) · H2OOrth. mm2 : Pmn21
19.12.6RobertsiteCa2Mn3+3(PO4)3O2 · 3H2OMon. m : Bb
19.12.7PararobertsiteCa2Mn3+3(PO4)3O2 · 3H2OMon. 2/m : P21/b
19.12.8SinkankasiteMn2+Al(PO3OH)2(OH) · 6H2OTric.
19.12.9MangangordoniteMn2+Al2(PO4)2(OH)2 · 8H2OTric.
19.12.10Heterosite(Fe3+,Mn3+)PO4Orth. mmm (2/m 2/m 2/m) : Pmna
19.12.11PurpuriteMn3+(PO4)Orth. mmm (2/m 2/m 2/m) : Pmna
19.12.12Wolfeite(Fe2+,Mn2+)2(PO4)(OH)Mon. 2/m : P21/b
19.12.13Triploidite(Mn2+,Fe2+)2(PO4)(OH)Mon. 2/m : P2/b
19.12.14LipscombiteFe2+Fe3+2(PO4)2(OH)2Tet.
19.12.15FrondeliteMn2+Fe3+4(PO4)3(OH)5Orth. 2 2 2 : C2 2 21
19.12.16RockbridgeiteFe2+Fe3+4(PO4)3(OH)5Orth. mmm (2/m 2/m 2/m)
19.12.17Kryzhanovskite(Fe3+,Mn2+)3(PO4)2(OH,H2O)3Orth.
19.12.18LandesiteMn2+3-xFe3+x(PO4)2(OH)x · (3-x)H2OOrth.
19.12.19Phosphoferrite(Fe2+,Mn2+)3(PO4)2 · 3H2OOrth. mmm (2/m 2/m 2/m) : Pmna
19.12.20Reddingite(Mn2+,Fe2+)3(PO4)2 · 3H2OOrth. mmm (2/m 2/m 2/m) : Pmna
19.12.21EarlshannoniteMn2+Fe3+2(PO4)2(OH)2 · 4H2OMon.
19.12.22Hureaulite(Mn,Fe)5(PO4)2(HPO4)2 · 4H2OMon. 2/m : B2/b
19.12.23SwitzeriteMn2+3(PO4)2 · 7H2OMon.
19.12.24LaueiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
19.12.25PseudolaueiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OMon. 2/m : P21/b
19.12.26StrunziteMn2+Fe3+2(PO4)2(OH)2 · 6H2OTric. 1 : P1
19.12.27StewartiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
19.12.28Alluaudite(Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3Mon.
19.12.29Ferroalluaudite(Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3Mon. 2/m : B2/b
19.12.30Fillowite{Mn2+}{Na8}{Ca4Na4}{(Mn2+,Fe2+)43}(PO4)36Trig. 3 : R3
19.12.31JohnsomervilleiteNa10Ca6Mg18Fe25(PO4)36Trig.
19.12.32WicksiteNaCa2(Fe2+,Mn2+)4MgFe3+(PO4)6 · 2H2OOrth. mmm (2/m 2/m 2/m)
19.12.33Dickinsonite-(KMnNa){KNa}{Mn2+◻}{Ca}{Na3}{Mn2+13}{Al}(PO4)12(OH)2Mon. 2/m : B2/b
19.12.34Sarcopside(Fe2+,Mn2+,Mg)3(PO4)2Mon. 2/m : P21/b
19.12.35LudlamiteFe2+3(PO4)2 · 4H2OMon. 2/m : P21/b
19.12.36GraftoniteFe2+Fe2+2(PO4)2Mon. 2/m : P21/b
19.12.37WilhelmvierlingiteCaMnFe3+(PO4)2(OH) · 2H2OOrth.
19.12.38FairfielditeCa2Mn2+(PO4)2 · 2H2OTric. 1 : P1
19.12.39BeusiteMn2+Mn2+2 (PO4)2Mon.
19.12.40MesseliteCa2Fe2+(PO4)2 · 2H2OTric. 1 : P1
19.12.41Jahnsite-(CaMnFe){Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
19.12.42Jahnsite-(CaMnMn){Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
19.12.43Jahnsite-(CaMnMg){Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
19.12.44KeckiteCaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 · 7H2OMon. 2/m : P2/b
19.12.45StanfielditeCa4Mg5(PO4)6Mon.
19.12.46Laubmannite(Fe2+,Mn2+,Ca)3Fe3+6(PO4)4(OH)12
19.12.47ZodaciteCa4Mn2+Fe3+4(PO4)6(OH)4 · 12H2OMon.
19.12.48HagendorfiteNaCaMn2+Fe2+2(PO4)3Mon. 2/m : B2/b
19.12.49Maghagendorfite(□,Na,)(Na,Ca,Fe2+)Mn(Mg,Fe2+,Fe3+)3(PO4)3Mon.
19.12.50VaruliteNaCaMn2+Mn2+2(PO4)3Mon. 2/m : B2/b
19.12.52Attakolite(Ca,Sr)Mn(Al,Fe)4(HPO4,PO4)3(SiO4,PO4)(OH)4Mon. 2/m : B2/m
19.12.53Arrojadite-(KFe){KNa}{Fe2+◻}{Ca}{Na2◻}{Fe2+13}{Al}(PO4)11(HPO4)(OH)2Mon.
19.12.54Lun'okite(Mn,Ca)(Mg,Fe,Mn)Al(PO4)2OH · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbca
19.12.55EosphoriteMn2+Al(PO4)(OH)2 · H2OOrth. mmm (2/m 2/m 2/m) : Cmca
19.12.56Ernstite(Mn2+,Fe3+)Al(PO4)(OH,O)2 · H2OMon.
19.12.57ChildreniteFe2+Al(PO4)(OH)2 · H2OOrth. mm2 : Ccc2
19.12.58BobfergusoniteNa2Mn5FeAl(PO4)6Mon. 2/m : P2/b
19.12.59QingheiiteNaMn3+Mg(Al,Fe3+)(PO4)3Mon. 2/m : P21/b
19.12.60Whiteite-(CaFeMg){Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P21/b
19.12.61Whiteite-(CaMnMg){Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m
19.12.62Whiteite-(MnFeMg){(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P21/b
19.12.63Rittmannite{(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2OMon.
19.12.64ZanazziiteCa2Mg5Be4(PO4)6(OH)4 · 6H2OMon. 2/m : B2/b
19.12.65Samuelsonite(Ca,Ba)Ca8Fe2+2Mn2+2Al2(PO4)10(OH)2Mon. 2/m : B2/m

Other InformationHide

Notes:
Readily soluble in acids.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for GriphiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Eains (1890) USGS Bulletin 60: 135.
Headden (1891) American Journal of Science: 41: 415.
Larsen, E.S. (1921) The Microscopic Determination of the Nonopaque Minerals, First edition, USGS Bulletin 679: 81.
McConnell (1942) American Mineralogist: 27: 452.
Jaffe (1946) American Mineralogist: 31: 404 (Dwiggins & Yelmgren analysis).
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 843-844.
American Mineralogist (1979): 64: 1333.
Bulletin de Mineralogie: 101: 543.

Internet Links for GriphiteHide

Localities for GriphiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Argentina
 
  • La Rioja Province
    • General Ángel V. Peñaloza Department
Fernando Colombo, Edgardo Baldo, Agustín Kriscautzky, Elisa V. Pannunzio Miner (2018) Metamictic griphite from the difunta correa pegmatite, sierra de los llanos, la rioja (Argentina). in abstracts of the 22nd IMA Meeting Melbourne p 495
Australia
 
  • Northern Territory
    • Central Desert Region
      • Delmore Downs station
        • Mount Ida
Jaffe 1946 Am Min
Canada
 
  • Manitoba
T.S. Ercit Can. Museum of Nature pers. comm.
France
 
  • Occitanie
    • Pyrénées-Orientales
      • Albères massif
        • L'Albère
          • Saint-Jean de l'Albère
Guitard, G. (2010): Catalogue raisonné de la collection de minéralogie régionale, C.E.R.P. de Tautavel, 110.
Rwanda
 
  • Western Province
    • Ngororero District
      • Gatumba
Daltry, V.D.C. and von Knorring, O. (1998) Type-mineralogy of Rwanda with particular reference to the Buranga pegmatite. Geologica Belgica: 1: 9-15.
USA (TL)
 
  • South Dakota
    • Pennington Co.
      • Harney City
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 844; Nickel & Nichols (1991) "Mineral Reference Manual".
      • Keystone Mining District
        • Keystone
USGS Bull 380D
R&M 75:3 pp 156-169
  • Wisconsin
    • Florence Co.
      • Fern
        • Pine River pegmatites
Falster, A. , W.B. Simmons & P.B. Moore (1996) The mineralogy and geochemistry of the Animikie Red Ace pegmatite in Florence County, Wisconsin: Recent Research Developments in Mineralogy: 1: 7-67.
 
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