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Gismondine-Ca

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About Gismondine-CaHide

Formula:
CaAl2Si2O8 · 4H2O
Crystal System:
Monoclinic
Member of:
Name:
The root name is for Carlo Giuseppe Gismondi (1762-1824), Italian mineralogist, who previously discovered "zeagonite" - a mixture of gismondine and phillipsite. The suffix denotes the dominant extra-framework cation.
At present (2006) the name approved by IMA CNMNC (after Zeolites Subcommittee) is simply gismondine.
All gismondines found and studied over almost two centuries were calcium-dominant.
Recently, a barium-dominant gismondine, "gismondine-Ba" has been discovered in slag material (of course not approved, as valid species, by IMA CNMNC). Therefore, in keeping with the recommendation of the Zeolite Subcommittee, "gismondine" acquired the status of series, and any individual species has to be denoted now with the suffix for the dominant extra-framework cation (e.g., gismondine-Ca, gismondine-Ba).



Classification of Gismondine-CaHide

Approved
9.GC.05

9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
C : Chains of doubly-connected 4-membered rings
16.9.25

16 : Silicates Containing Aluminum and other Metals
9 : Aluminosilicates of Ca

Chemical Properties of Gismondine-CaHide

Formula:
CaAl2Si2O8 · 4H2O

Crystallography of Gismondine-CaHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 10.02(3) Å, b = 10.61(5) Å, c = 9.843(15) Å
Ratio:
a:b:c = 0.944 : 1 : 0.928
Unit Cell V:
0.00 ų (Calculated from Unit Cell)

Synonyms of Gismondine-CaHide

Other Language Names for Gismondine-CaHide

German:Aricit

Relationship of Gismondine-Ca to other SpeciesHide

Member of:
Other Members of this group:
AlflarseniteNaCa2Be3Si4O13(OH) · 2H2OMon. 2 : P21
AmiciteK2Na2Al4Si4O16 · 5H2OMon. 2
Ammonioleucite(NH4)(AlSi2O6)Tet.
AnalcimeNa(AlSi2O6) · H2OTric. 1 : P1
Bellbergite(K,Ba,Sr)2Sr2Ca2(Ca,Na)4[Al3Si3O12]6 · 30H2OHex.
BikitaiteLiAlSi2O6 · H2OTric. 1 : P1
BoggsiteCa8Na3(Si,Al)96O192 · 70H2OOrth. mmm (2/m 2/m 2/m) : Imma
Brewsterite-Ba(Ba,Sr)[Al2Si6O16] · 5H2OMon. 2/m : P21/m
Brewsterite-Sr(Sr,Ba,Ca)[Al2Si6O16] · 5H2OMon. 2/m : P21/m
Chabazite-Levyne SubgroupA subgroup of the Zeolite Group.
ChiavenniteCaMnBe2Si5O13(OH)2 · 2H2OMon. 2/m : P21/b
ClinoptiloliteNote on the distinguishing differences between clinoptilolite and heulandite (http://rruff.
CowlesiteCaAl2Si3O10 · 6H2OOrth.
Dachiardite-Ca(Ca,Na2,K2)5Al10Si38O96 · 25H2OMon.
Dachiardite-KK4(Si20Al4O48)·13H2OMon.
Dachiardite-Na(Na2,Ca,K2)5Al10Si38O96 · 25H2OMon.
DirenzoiteNaK6MgCa2(Al13Si47O120) · 36H2OOrth. mmm (2/m 2/m 2/m) : Pmmn
EdingtoniteBa[Al2Si3O10] · 4H2OOrth. 2 2 2 : P21 21 21
EpistilbiteCaAl2Si6O16 · 5H2OMon.
ErioniteThis name now refers to a group of related minerals.
Faujasite
Faujasite-Ca(Ca,Na2,Mg)3.5[Al7Si17O48] · 32H2OIso.
FerrieriteZeolite Group.
FerrochiavenniteCa1-2Fe[(Si,Al,Be)5Be2O13(OH)2] · 2H2OMon. 2/m : P21/b
Flörkeite(K3Ca2Na)[Al8Si8O32] · 12H2OTric. 1 : P1
Garronite-CaNa2Ca5Al12Si20O64 · 27H2OTet. 4 2m : I4m2
GaultiteNa4Zn2Si7O18 · 5H2OOrth. mm2 : Fdd2
Gismondine-BaBa2Al4Si4O16 · 4-6H2O
GmeliniteIn 1997, gmelinite was split into Gmelinite-Ca, Gmelinite-Na and Gmelinite-K.
GobbinsiteNa5(Si11Al5)O32 · 11H2OOrth.
GoosecreekiteCa[Al2Si6O16] · 5H2OMon.
GottardiiteNa3Mg3Ca5Al19Si117O272 · 93H2OOrth.
HeulanditeNote on the distinguishing differences between heulandite and clinoptilolite (http://rruff.
HsianghualiteCa3Li2(Be3Si3O12)F2Iso. 4 3 2 : I41 3 2
KirchhoffiteCs(BSi2O6)Tet. 4/mmm (4/m 2/m 2/m) : I41/acd
LaumontiteCaAl2Si4O12 · 4H2OMon. 2/m : B2/m
LovdariteK2Na6Be4Si14O36 · 9H2OOrth. mm2
MaricopaitePb7Ca2(Si,Al)48O100 · 32H2OOrth.
MartinandresiteBa2(Al4Si12O32)·10H2OOrth. mmm (2/m 2/m 2/m) : Pmmn
Mazzite-Mg(Mg,K,Ca)5(Si26Al10)O72 · 28H2OHex.
Mazzite-NaNa8[Al4Si14O36]2 · 30H2OHex. 6/mmm (6/m 2/m 2/m) : P63/mmc
Merlinoite(K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2OOrth.
Montesommaite(K,Na)9Al9Si23O64 · 10H2OOrth.
Mordenite(Na2,Ca,K2)4(Al8Si40)O96 · 28H2OOrth.
MutinaiteNa3Ca4Si85Al11O192 · 60H2OOrth.
NabesiteNa2BeSi4O10 · 4H2OOrth. 2 2 2 : P21 21 21
Natrolite SubgroupA subgroup of the Zeolite Group.
OffretiteKCaMg(Si13Al5)O36 · 15H2OHex. 6 m2 : P6m2
PahasapaiteLi8(Ca,Li,K)10.5Be24(PO4)24 · 38H2OIso. 2 3 : I2 3
ParthéiteCa2(Si4Al4) O15 (OH)2•4H2OMon. 2/m : B2/b
Paulingite-Ca(Ca,K,Na,Ba,◻)10 (Si, Al)42O84•34H2OIso.
Paulingite-K(K2,Ca,Na2,Ba)5[Al10Si35O90] · 45H2OIso.
Paulingite-Na(Na2,K2,Ca,Ba)5[Al10Si35O90] · 45H2OIso.
PerlialiteK9Na(Ca,Sr)[Al2Si4O12]6 · 15H2OHex.
PhillipsiteZeolite Group.
Pollucite(Cs,Na)2(Al2Si4O12) · 2H2OIso. m3m (4/m 3 2/m) : Ia3d
RoggianiteCa2Be(OH)2Al2Si4O13 · 2.5H2OTet.
Stilbite subgroupThis name now refers to the zeolite subgroup including the Barrerite - Stilbite-Ca - ...
Terranovaite(Na,Ca)8(Si68Al12)O160 · 29H2OOrth.
Thomsonite-CaNaCa2[Al5Si5O20] · 6H2OOrth. mmm (2/m 2/m 2/m)
Thomsonite-SrNa(Sr,Ca)2[Al5Si5O20] · 7H2OOrth. mmm (2/m 2/m 2/m)
Tschernichite(Ca,Na2)[Al2Si4O12] · 4-8H2OTet. 4/mmm (4/m 2/m 2/m) : P4/mmm
TschörtneriteCa4(Ca,Sr,K,Ba)3Cu3[Al3Si3O12]4(OH)8 · nH2OIso. m3m (4/m 3 2/m) : Fm3m
UM1996-38-SiO:AlCaHNaNa-Ca-Al-Si-O-H
UM1999-33-SiO:AlHKNaK7Na5Al12Si20O64•24H2O
WairakiteCa(Al2Si4O12) · 2H2OMon. 2/m
WeinebeneiteCaBe3(PO4)2(OH)2 · 4H2OMon.
Wenkite(Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2OHex.
WillhendersoniteKCa[Al3Si3O12] · 5H2OTric.
YugawaraliteCaAl2Si6O16 · 4H2OMon.

Common AssociatesHide

Associated Minerals Based on Photo Data:
6 photos of Gismondine-Ca associated with Chabazite-Ca(Ca,K2,Na2)2[Al2Si4O12]2 · 12H2O
4 photos of Gismondine-Ca associated with Phillipsite
2 photos of Gismondine-Ca associated with Flörkeite(K3Ca2Na)[Al8Si8O32] · 12H2O
2 photos of Gismondine-Ca associated with Thomsonite-CaNaCa2[Al5Si5O20] · 6H2O
1 photo of Gismondine-Ca associated with CalciteCaCO3
1 photo of Gismondine-Ca associated with Tobermorite[Ca4Si6O17 · 2H2O]·(Ca·3H2O)
1 photo of Gismondine-Ca associated with PyriteFeS2
1 photo of Gismondine-Ca associated with WollastoniteCaSiO3
1 photo of Gismondine-Ca associated with WillhendersoniteKCa[Al3Si3O12] · 5H2O
1 photo of Gismondine-Ca associated with Phillipsite-Ca(Ca0.5,K,Na,Ba0.5)4-7[Al4-7Si12-9O32] . 12H2O

Related Minerals - Nickel-Strunz GroupingHide

9.GC.05AmiciteK2Na2Al4Si4O16 · 5H2OMon. 2
9.GC.05Garronite-CaNa2Ca5Al12Si20O64 · 27H2OTet. 4 2m : I4m2
9.GC.05GobbinsiteNa5(Si11Al5)O32 · 11H2OOrth.
9.GC.10Harmotome(Ba0.5,Ca0.5,K,Na)5[Al5Si11O32] · 12H2OMon. 2/m : P21/m
9.GC.10Phillipsite-Ca(Ca0.5,K,Na,Ba0.5)4-7[Al4-7Si12-9O32] . 12H2OMon. 2/m : P21/m
9.GC.10Phillipsite-K(K,Na,Ca0.5,Ba0.5)4-7[Al4-7Si12-9O32] . 12H2OMon. 2/m : P21/m
9.GC.10Phillipsite-Na(Na,K,Ca0.5,Ba0.5)4-7[Al4-7Si12-9O32] · 12H2OMon.
9.GC.10Flörkeite(K3Ca2Na)[Al8Si8O32] · 12H2OTric. 1 : P1
9.GC.15Merlinoite(K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2OOrth.
9.GC.20Mazzite-Mg(Mg,K,Ca)5(Si26Al10)O72 · 28H2OHex.
9.GC.20Mazzite-NaNa8[Al4Si14O36]2 · 30H2OHex. 6/mmm (6/m 2/m 2/m) : P63/mmc
9.GC.25PerlialiteK9Na(Ca,Sr)[Al2Si4O12]6 · 15H2OHex.
9.GC.30BoggsiteCa8Na3(Si,Al)96O192 · 70H2OOrth. mmm (2/m 2/m 2/m) : Imma
9.GC.35Paulingite-Ca(Ca,K,Na,Ba,◻)10 (Si, Al)42O84•34H2OIso.
9.GC.35Paulingite-K(K2,Ca,Na2,Ba)5[Al10Si35O90] · 45H2OIso.

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

16.9.1GehleniteCa2Al(AlSiO7)Tet. 4 2m : P4 21m
16.9.2AnorthiteCa(Al2Si2O8)Tric. 1 : P1
16.9.3Yoshiokaite(Ca,Na)[Al(Al,Si)O4]Trig. 3 : P3
16.9.4SvyatoslaviteCa(Al2Si2O8)Orth.
16.9.5DmisteinbergiteCa(Al2Si2O8)Trig. 3 2 : P3 1 2
16.9.6GrossularCa3Al2(SiO4)3Iso. m3m (4/m 3 2/m) : Ia3d
16.9.7VuagnatiteCaAl(SiO4)(OH)Orth.
16.9.8ZoisiteCa2Al3[Si2O7][SiO4]O(OH)Orth. mmm (2/m 2/m 2/m) : Pnma
16.9.9Clinozoisite{Ca2}{Al3}(Si2O7)(SiO4)O(OH)Mon. 2/m : P21/m
16.9.10PrehniteCa2Al2Si3O10(OH)2Orth. mm2
16.9.11KamaishiliteCa2(Al2SiO6)(OH)2Tet.
16.9.12BicchuliteCa2(Al2SiO6)(OH)2Iso. 4 3m : I4 3m
16.9.13MargariteCaAl2(Al2Si2O10)(OH)2Mon.
16.9.14ChantaliteCaAl2(SiO4)(OH)4Tet. 4/m : I41/a
16.9.15CebolliteCa5Al2(SiO4)3(OH)4Orth.
16.9.17KatoiteCa3Al2(SiO4)3-x(OH)4x (x = 1.5-3)Iso.
16.9.18LawsoniteCaAl2(Si2O7)(OH)2 · H2OOrth. mmm (2/m 2/m 2/m) : Cmcm
16.9.19ParthéiteCa2(Si4Al4) O15 (OH)2•4H2OMon. 2/m : B2/b
16.9.20WairakiteCa(Al2Si4O12) · 2H2OMon. 2/m
16.9.21VertumniteCa4Al4Si4O6(OH)24 · 3H2OMon. 2/m : P21/m
16.9.22ScoleciteCaAl2Si3O10 · 3H2OMon. m : Bb
16.9.23LaumontiteCaAl2Si4O12 · 4H2OMon. 2/m : B2/m
16.9.24YugawaraliteCaAl2Si6O16 · 4H2OMon.
16.9.26EpistilbiteCaAl2Si6O16 · 5H2OMon.
16.9.27GoosecreekiteCa[Al2Si6O16] · 5H2OMon.
16.9.28CowlesiteCaAl2Si3O10 · 6H2OOrth.
16.9.30StelleriteCa4(Si28Al8)O72 · 28H2OOrth. mmm (2/m 2/m 2/m) : Fmmm
16.9.31SträtlingiteCa2Al2SiO7 · 8H2OTrig.
16.9.32AmstalliteCaAl(Si,Al)4O8(OH)4 · (H2O,Cl)Mon. 2/m : B2/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Gismondine-CaHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Von Leonhard, K.C. (1817): Die Zeagonit, ein neues Mineral vom Capo di Bove bei Rom. Taschenbuch für die gesammte Mineralogie, 11, 164-168.
Gismondi, C.G. (1817): Osservazioni sopra alcuni fossili particolari de’ contorni di Roma. Giornale Enciclopedico di Napoli, 2/11, 3-15.
Walker, G.P.L. (1962): Low-potash gismondine from Ireland and Iceland. Mineralogical Magazine, 33, 187-201.
Fischer, K. (1963): The crystal structure determination of the zeolite gismondite. CaAl2Si2O8•4H2O. American Mineralogist, 48, 664-672.
Vezzalini, G. & Oberti, R. (1984): The crystal chemistry of gismondines; the non-existence of K-rich gismondines. Bulletin de Minéralogie, 107, 805-812.
Artioli, G., Rinaldi, R., Kvick, A., Smith, J.V. (1986): Neutron diffraction structure refinement of the zeolite gismondine at 15 K. Zeolites, 6, 361-366.
Rinaldi, R. & Vezzalini, G. (1986): Gismondine: the detailed X-ray structure refinement of two natural samples. In "Zeolites: Synthesis, Structure, Technology and Application", B. Drzaj, S. Hocevar, S. Pejovnik, eds. Elsevier, Amsterdam, 481-492.
Yoshida, A. (1995): The problems of identifications of phillipsite and gismondine crystal structures and X-ray diffraction patterns. Clay Science, 9, 275-284.
Coombs, D.S., Alberti, A., Armbruster, T., Artioli, G., Colella, C., Galli, E., Grice, J.D., Liebau, F., Mandarino, J.A., Minato, H., Nickel, E.H., Passaglia, E., Peacor, D.R., Quartieri, S., Rinaldi, R., Ross, M., Sheppard, R.A., Tillmanns, E., Vezzalini, G. (1997): Recommended nomenclature for zeolites minerals - Report of the Subcommittee on Zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names. [Review]. Canadian Mineralogist, 35, 1571-1606.

Internet Links for Gismondine-CaHide

Localities for Gismondine-CaHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Austria
 
  • Styria
    • Graz-Umgebung District
      • Frohnleiten
        • Kirchdorf
Kolitsch, U. et al. (2008)
Canada
 
  • Québec
    • Laurentides
      • Argenteuil RCM
        • Wentworth
          • Laurel
TARASSOFF, P., HORVÁTH, L. and PFENNINGER-HORVÁTH, E. (2006) Famous mineral localities: the Francon quarry, Montréal, Québec. Mineralogical Record, 37, 5-60.
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
GRICE, J.D. (1989) Mont Saint-Hilaire, Quebec: Canada's Most Diverse Mineral Locality. In: Famous mineral localities of Canada. Published by Fitzhenry & Whiteside Limited & the National Museum of Natural Sciences, 190 pages: 100-108; 166-175.; HORVÁTH, L., GAULT, R.A. (1990) The mineralogy of Mont Saint-Hilaire. Mineralogical Record, 21, 281-359.
    • Montréal
TARASSOFF, P., HORVÁTH, L. and PFENNINGER-HORVÁTH, E. (2006) Famous mineral localities: the Francon quarry, Montréal, Québec. Mineralogical Record, 37, 5-60.
Czech Republic
 
  • Ústí nad Labem Region
    • Děčín District
      • Česká Kamenice
-P.Pauliš,L.Hrůzek,O.Janeček,J.Sejkora,R.Malíková(2014):Cowlesit a doprovodná mineralizace z vrchu Hackenberg u České Kamenice.Bulletin mineralogicko-petrologického oddělení Národní muzeum Praha-2/2014
Rychlý, R., Bárta, J., Fišera, V. (1980): Nové nálezy gismondinu na Děčínsku. Časopis pro mineralogii a geologii, roč. 25, č. 1, s. 69-72.
No reference listed
France
 
  • Auvergne-Rhône-Alpes
    • Loire
      • Montbrison
        • Verrières-en-Forez
Lacroix A. (1893) - Minéralogie de la France et des ses colonies, Volume 2, p. 323
Germany
 
  • Rhineland-Palatinate
    • Ahrweiler
      • Brohltal
        • Brenk
Hentschel, G., Die Mineralien der Eifelvulkane, Weise Verlag München, 1983
        • Niederzissen
          • Hannebach
Hentschel, G., Die Mineralien der Eifelvulkane, Weise Verlag, München (2. Auflage), 1987
    • Mayen-Koblenz
      • Bell
Hentschel, G., Die Mineralien der Eifelvulkane, Weise Verlag München, 1983
      • Mayen
        • Bellerberg volcano
          • Southern lava flow
            • Mayener Feld
Peacor, D.R., Dunn, P.J., Simmons, W.B., Tillmanns, E., Fischer, R.X., (1984): Willhendersonite, a new zeolite isostructural with chabazite, Amer. Mineral. 69, 186-189
        • Ettringen
          • Bellerberg volcano
Hentschel, G., Die Mineralien der basaltischen Gesteine im Laacher Vulkangebiet, Aufschluß 26, 65-87, 1975
    • Vulkaneifel
      • Birresborn
Hentschel, G., Die Mineralien der Eifelvulkane, Weise Verlag, München (2. Auflage), 1987
      • Daun
        • Üdersdorf
Schüller, W., Betz, V., Die Mineralien vom Emmelberg, Lapis 12/1986
Hentschel, G., Die Mineralien der Eifelvulkane, Weise Verlag München, 1983
      • Gerolstein
        • Rockeskyll
          • Rockeskyll volcanic complex
Hentschel, G., (1987): Die Mineralien der Eifelvulkane, Weise Verlag München
      • Hillesheim
Hentschel, G., Die Lavaströme der Graulai: eine neue Fundstelle in der Westeifel, Lapis, Weise Verlag München, 09/1993
        • Zilsdorf
Hentschel, G. (1973) Begleitmineralien des Basaltes vom Arensberg bei Zilsdorf, Eifel. Notizbl. hess. L.-Amt Bodenforsch. 101, 310-316.; Doornveld, H.Y. (1987) Enkele mineraalvoorkomens in de Eifel. GEA, 20 (1), 32-36 (in Dutch).
Italy
 
  • Campania
    • Naples
      • Somma-Vesuvius Complex
        • Mt Vesuvius
          • Terzigno
Russo, M., Punzo, I. (2004): I minerali del Somma-Vesuvio, AMI
  • Lazio
    • Metropolitan City of Rome Capital
      • Rome
Christof Schäfer
        • Osteria dell'Osa
Antonio Borrelli collection
Mexico
 
  • Zacatecas
    • Concepción del Oro Municipality
New Zealand
 
  • Northland Region
    • Kaipara District
      • Aranga
Rod Martin personal collection
  • Otago Region
    • Dunedin City
Graham, I.T. , Pogson, R.E., Colchester, D.M. & Baines, A. (2003) Zeolite crystal habits , composition, and paragenesis; Blackhead Quarry, Dunedin, New Zealand - Mineralogical Magazine, 67, 625-737
Spain
 
  • Castile-La Mancha
    • Ciudad Real
Calvo, M., Calvo Sevillano, G., Viñals, J. y Sanz, A. (2010). Presencia de ettringita y thaumasita en vacuolas de los basaltos del Campo de Calatrava (Ciudad Real). Macla, 11, 53-54.
        • Almagro
Calvo, M., Viñals, J., Sanz, A. and Martí, J. (2013). Zeolites and asociated minerals in the vacuoles of some of the Campo de calatrava volcanoes - Ciudad Real, Spain. Mineral Up,3, 54-69
Calvo, M., Viñals, J., Sanz, A. and Martí, J. (2013). Zeolites and asociated minerals in the vacuoles of some of the Campo de calatrava volcanoes - Ciudad Real, Spain. Mineral Up,3, 54-69
UK
 
  • Northern Ireland
    • Ulster
      • Co. Antrim
        • Ballyclare
G.P.L. Walker and I.S.E. Carmichael (1962) Low-Potash Gismondine from Ireland and Iceland. Mineralogical Magazine vol. 33, n° 258, 187-201.; Peter Francis (1972) The Occurrence of Native Copper in the Tertiary Basalts of Co. Antrim. The Irish Naturalists' Journal 17:274-276.; Embrey, P.G. (1978) Fourth supplementary list of British minerals. Mineralogical Magazine, vol. 42, n° 322, 169-177.
No reference listed
USA
 
  • Arizona
    • Maricopa Co.
  • Hawaii
    • Honolulu Co.
      • Oahu
No reference listed
American Mineralogist (1969) 54:182-197
    • Kauai Co.
      • Kauai Island
Handbook of Mineralogy
 
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