Gadolinite-(Ce)
A valid IMA mineral species
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About Gadolinite-(Ce)
Johan Gadolin
Formula:
(Ce,La,Nd,Y)2Fe2+Be2Si2O10
Often slightly radioactive due to minor U and/or Th contents; therefore often metamict.
Colour:
Black
Lustre:
Vitreous
Hardness:
6½ - 7
Specific Gravity:
4.20
Crystal System:
Monoclinic
Member of:
Name:
Named for its relationship to gadolinite-(Y), but with cerium as the dominant rare earth element. Gadolinite honors Johan Gadolin (5 June 1760, Turku, Finland - 15 August 1852, Mynämäki, Finland), chemist, physicist, and mineralogist.
Type Locality:
The cerium analogue of Gadolinite-(Y) and Gadolinite-(Nd).
At the type locality, gadolinite-(Ce) often occurs with an orange or yellow alteration rim (up to 0.5 mm).
The Italian occurrences of gadolinite-(Ce) are not probed by analyses and most correctly they should be classified as "gadolinite" (s.l.).
At the type locality, gadolinite-(Ce) often occurs with an orange or yellow alteration rim (up to 0.5 mm).
The Italian occurrences of gadolinite-(Ce) are not probed by analyses and most correctly they should be classified as "gadolinite" (s.l.).
Unique Identifiers
Mindat ID:
1627
Long-form identifier:
mindat:1:1:1627:4
GUID
(UUID V4):
(UUID V4):
bea40de9-1e6b-4185-8bcd-93c6a2ef2b87
IMA Classification of Gadolinite-(Ce)
Approved
IMA Formula:
Ce2Fe2+Be2O2(SiO4)2
Approval year:
1987
First published:
1978
Classification of Gadolinite-(Ce)
9.AJ.20
9 : SILICATES (Germanates)
A : Nesosilicates
J : Nesosilicates with BO3 triangles and/or B[4], Be[4] tetrahedra, cornersharing with SiO4
9 : SILICATES (Germanates)
A : Nesosilicates
J : Nesosilicates with BO3 triangles and/or B[4], Be[4] tetrahedra, cornersharing with SiO4
54.2.1b.2
54 : NESOSILICATES Borosilicates and Some Beryllosilicates
2 : Borosilicates and Some Beryllosilicates with B in [4] coordination
54 : NESOSILICATES Borosilicates and Some Beryllosilicates
2 : Borosilicates and Some Beryllosilicates with B in [4] coordination
14.3.24
14 : Silicates not Containing Aluminum
3 : Silicates of Be
14 : Silicates not Containing Aluminum
3 : Silicates of Be
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference |
|---|---|---|
| Gad-Ce | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Gad | Siivolam & Schmid (2007) | Siivolam, J. and Schmid, R. (2007) Recommendations by the IUGS Subcommission on the Systematics of Metamorphic Rocks: List of mineral abbreviations. Web-version 01.02.07. IUGS Commission on the Systematics in Petrology. download |
Physical Properties of Gadolinite-(Ce)
Vitreous
Colour:
Black
Comment:
Olive green in thin sections
Hardness:
6½ - 7 on Mohs scale
Fracture:
Conchoidal
Density:
4.20 g/cm3 (Measured)
Optical Data of Gadolinite-(Ce)
Type:
Biaxial (-)
RI values:
nα = 1.780 nβ = 1.800 nγ = 1.810
2V:
Measured: 70° (5)
Birefringence:
mid-2nd order birefringence
Max Birefringence:
δ = 0.030
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Very High
Pleochroism:
Non-pleochroic
Comments:
pale yellow-green in thin section
Comments:
The mineral is reported in numerous sources as "isotropic" with n = 1.78, but as the mineral is monoclinic, this observation was clearly done on metamict material. This assertion appears to derive from an observation on material only from Skien, Norway (Segalstad & Larsen, 1978). In contrast to the Norwegian sample, gadolinite-(Ce) from the Malmkärra mine, Norberg, Sweden is U-free and Th-free and is non-metamict. This material shows normal anisotropic optical properties consistent with a monoclinic symmetry (non-zero birefringence; biaxial nature).
Note that in the absence of measured R.I. data for anisotropic gadolinite-(Ce), the listed R.I. values above are those of the analogous species gadolinite-(Nd) (but no estimate of errors is attempted). However, these values nonetheless successfully reproduce the observed birefringence and 2V° of the Malmkärra mine gadolinite-(Ce). Not unexpectedly, the overall optical properties of non-metamict gadolinite-(Ce) appear to be largely comparable to those of gadolinite-(Nd).
Note that in the absence of measured R.I. data for anisotropic gadolinite-(Ce), the listed R.I. values above are those of the analogous species gadolinite-(Nd) (but no estimate of errors is attempted). However, these values nonetheless successfully reproduce the observed birefringence and 2V° of the Malmkärra mine gadolinite-(Ce). Not unexpectedly, the overall optical properties of non-metamict gadolinite-(Ce) appear to be largely comparable to those of gadolinite-(Nd).
Chemistry of Gadolinite-(Ce)
Mindat Formula:
(Ce,La,Nd,Y)2Fe2+Be2Si2O10
Often slightly radioactive due to minor U and/or Th contents; therefore often metamict.
Often slightly radioactive due to minor U and/or Th contents; therefore often metamict.
Crystallography of Gadolinite-(Ce)
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 9.8973 Å, b = 7.6282 Å, c = 4.7505 Å
β = 90.416°
β = 90.416°
Ratio:
a:b:c = 1.297 : 1 : 0.623
Unit Cell V:
358.65 ų (Calculated from Unit Cell)
Comment:
Space group P2/c was determined for material heated at 700oC
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 6.06 Å | (42) |
| 3.74 Å | (37) |
| 3.44 Å | (34) |
| 3.13 Å | (86) |
| 2.85 Å | (100) |
| 2.56 Å | (46) |
| 2.21 Å | (33) |
| 1.976 Å | (30) |
Comments:
Spacings for the material hydrothermally recrystallized at 700oC: 2.88 (100), 4.81 (90), 2.60 (80), 2.59 (80), 3.18 (70), 3.00 (70), and 3.59 (60)
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| High-𝑇 alteration and/or metamorphism | |
| 31 : Thermally altered carbonate, phosphate, and iron formations | |
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 34 : Complex granite pegmatites | |
| 35 : Ultra-alkali and agpaitic igneous rocks |
Type Occurrence of Gadolinite-(Ce)
General Appearance of Type Material:
Black irregular masses up to 20 mm in matrix.
Place of Conservation of Type Material:
Mineralogical-Geological Museum, University of Oslo, Oslo, Norway, number 21325.
Chemical Analysis of Type Material:
| SiO2 | 22.99 % |
|---|---|
| BeO | 8.83 % |
| Al2O3 | 0.02 % |
| B2O3 | 0.55 % |
| TiO2 | 0.25 % |
| FeO | 10.65 % |
| MnO | 1.89 % |
| MgO | 0.33 % |
| CaO | 2.15 % |
| Na2O | 0.11 % |
| K2O | 0.52 % |
| Y2O3 | 14.82 % |
| La2O3 | 9.07 % |
| Ce2O3 | 15.55 % |
| Total: | 87.73 % |
Geological Setting of Type Material:
Syenite pegmatite.
Associated Minerals at Type Locality:
Reference:
Segalstad, T. V. & Larsen, A. O. (1978): Gadolinite-(Ce) from Skien, southwestern Oslo Region, Norway. American Mineralogist 63: 188-195
Synonyms of Gadolinite-(Ce)
Gadolinite (in part)
Other Language Names for Gadolinite-(Ce)
Relationship of Gadolinite-(Ce) to other Species
Member of:
Other Members of this group:
| Calcybeborosilite-(Y) | (Y,Ca)2(◻,Fe2+)(B,Be)2[SiO4]2(OH,O)2 | Mon. |
| Gadolinite-(Nd) | Nd2Fe2+Be2O2(SiO4)2 | Mon. 2/m : P21/b |
| Gadolinite-(Y) | Y2Fe2+Be2Si2O10 | Mon. 2/m : P21/b |
| Hingganite-(Ce) | (Ce,REE)2(◻,Fe2+)Be2[SiO4]2(OH)2 | Mon. 2/m : P21/b |
| Hingganite-(Nd) | Nd2◻Be2Si2O8(OH)2 | Mon. 2/m : P21/b |
| Hingganite-(Y) | (Y,REE,Ca)2(◻,Fe2+)Be2[SiO4]2(OH)2 | Mon. 2/m : P21/b |
| Hingganite-(Yb) | (Yb,Y,REE)2◻Be2[SiO4]2(OH)2 | Mon. 2/m : P21/b |
| Minasgeraisite-(Y) | (Ca2Y2)◻2(Be2B2)[SiO4]4(OH)4 | Tric. 1 : P1 |
| Unnamed (OH-analogue of Gadolinite-(Y)) | (Y,Ca)2(Fe,◻)Be2Si2O8(OH,O)2 | Mon. 2/m |
Common Associates
Associated Minerals Based on Photo Data:
| 5 photos of Gadolinite-(Ce) associated with Albite | Na(AlSi3O8) |
| 4 photos of Gadolinite-(Ce) associated with Quartz | SiO2 |
| 4 photos of Gadolinite-(Ce) associated with Microcline | K(AlSi3O8) |
| 4 photos of Gadolinite-(Ce) associated with Phenakite | Be2SiO4 |
| 2 photos of Gadolinite-(Ce) associated with Fluorite | CaF2 |
| 2 photos of Gadolinite-(Ce) associated with Thorite | Th(SiO4) |
| 2 photos of Gadolinite-(Ce) associated with Xenotime-(Y) | Y(PO4) |
| 2 photos of Gadolinite-(Ce) associated with Adularia | KAlSi3O8 |
| 2 photos of Gadolinite-(Ce) associated with Monazite-(Ce) | Ce(PO4) |
| 2 photos of Gadolinite-(Ce) associated with Annite | KFe2+3(AlSi3O10)(OH)2 |
Related Minerals - Strunz-mindat Grouping
| 9.AJ. | Hingganite-(Nd) | Nd2◻Be2Si2O8(OH)2 |
| 9.AJ. | Arrheniusite-(Ce) | CaMg[(Ce7Y3)Ca5](SiO4)4(Si2B3AsO18)(BO3)F11 |
| 9.AJ.05 | Grandidierite | (Mg,Fe2+)(Al,Fe3+)3(SiO4)(BO3)O2 |
| 9.AJ.05 | Ominelite | (Fe2+,Mg)(Al,Fe3+)3(SiO4)(BO3)O2 |
| 9.AJ.10 | Dumortierite | Al(Al2O)(Al2O)2(SiO4)3(BO3) |
| 9.AJ.10 | Holtite | (Ta0.6◻0.4)Al6BSi3O18(O,OH)2.25 |
| 9.AJ.10 | Magnesiodumortierite | Mg(Al2OH)(Al2O)2(SiO4)3(BO3) |
| 9.AJ.10 | Nioboholtite | (Nb0.6◻0.4)Al6BSi3O18 |
| 9.AJ.10 | Titanoholtite | (Ti0.75◻0.25)Al6BSi3O18 |
| 9.AJ.15 | Garrelsite | Ba3NaSi2B7O16(OH)4 |
| 9.AJ.20 | Muromontite | near Be2FeY2Si3O12 |
| 9.AJ.20 | Datolite | CaB(SiO4)(OH) |
| 9.AJ.20 | Gadolinite-(Y) | Y2Fe2+Be2Si2O10 |
| 9.AJ.20 | Hingganite-(Ce) | (Ce,REE)2(◻,Fe2+)Be2[SiO4]2(OH)2 |
| 9.AJ.20 | Hingganite-(Y) | (Y,REE,Ca)2(◻,Fe2+)Be2[SiO4]2(OH)2 |
| 9.AJ.20 | Hingganite-(Yb) | (Yb,Y,REE)2◻Be2[SiO4]2(OH)2 |
| 9.AJ.20 | Homilite | Ca2(Fe2+,Mg)B2Si2O10 |
| 9.AJ.20 | Melanocerite-(Ce) | (Ce,Ca)5(SiO4,BO4)3(OH,0) |
| 9.AJ.20 | Minasgeraisite-(Y) | (Ca2Y2)◻2(Be2B2)[SiO4]4(OH)4 |
| 9.AJ.20 | Calcybeborosilite-(Y) | (Y,Ca)2(◻,Fe2+)(B,Be)2[SiO4]2(OH,O)2 |
| 9.AJ.20 | Gadolinite-(Nd) | Nd2Fe2+Be2O2(SiO4)2 |
| 9.AJ.20 | Unnamed (OH-analogue of Gadolinite-(Y)) | (Y,Ca)2(Fe,◻)Be2Si2O8(OH,O)2 |
| 9.AJ.25 | Stillwellite-(Ce) | (Ce,La,Ca)BSiO5 |
| 9.AJ.30 | Cappelenite-(Y) | Ba(Y,Ce)6Si3B6O24F2 |
| 9.AJ.35 | Okanoganite-(Y) | (Na,Ca)3(Y,Ce)12Si6B2O27F14 |
| 9.AJ.35 | Vicanite-(Ce) | (Ca,Ce,La,Th)15As5+(As3+0.5,Na0.5)Fe3+Si6B4O40F7 |
| 9.AJ.35 | Hundholmenite-(Y) | (Y,REE,Ca,Na)15(Al,Fe3+)(CaxAs3+1-x)(Si,As5+)Si6B3(O,F)48 |
| 9.AJ.35 | Proshchenkoite-(Y) | Ca(Y,REE,Ca,Na,Mn)15Fe2+(P,Si)Si6B3O34F14 |
| 9.AJ.35 | Laptevite-(Ce) | Ca6(Fe2+,Mn2+)Y3REE7(SiO4)3(PO4)(B3Si3O18)(BO3)F11 |
| 9.AJ.40 | Jadarite | LiNaSiB3O7(OH) |
Other Information
Thermal Behaviour:
DTA shows a broad and indistinct exotherm at about 250-350 °C and a large exotherm at 790 °C grading into a smaller exotherm at 8l0 °C.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Gadolinite-(Ce)
mindat.org URL:
https://www.mindat.org/min-1627.html
Please feel free to link to this page.
Please feel free to link to this page.
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References for Gadolinite-(Ce)
Reference List:
Segalstad, Tom Victor, Larsen, Alf Olav (1978) Gadolinite-(Ce) from Skien, southwestern Oslo region, Norway. American Mineralogist, 63 (1-2) 188-195
Anthony, John W., Bideaux, Richard A., Bladh, Kenneth W., Nichols, Monte C. - Eds. (2016) Handbook of Mineralogy. https://www.handbookofmineralogy.org/
Localities for Gadolinite-(Ce)
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Austria | |
| Wittern A. |
| Exel (1993) |
Germany | |
| |
Italy | |
| Thorne (n.d.) |
| |
| Carlini | |
| Grill (1935) |
| Pezzotta et al. (1999) |
| Folie et al. (2010) |
Mozambique | |
| Wilson et al. (2000) |
Norway | |
| Larsen et al. (2010) |
| Segalstad et al. (1978) |
| Knut Eldjarn | |
| Larsen et al. (1981, June) +1 other reference |
| Raade et al. (1983) | |
| Grice et al. (2013) | |
| Larsen et al. (1992) |
| Andresen (2011) |
| Larsen et al. (2010) | |
| Engvoldsen et al. (1991) |
| Hansen (1981) +1 other reference |
| Berge (n.d.) | |
| Engvoldsen et al. (1991) |
| Engvoldsen et al. (1991) |
| Engvoldsen et al. (1991) | |
| Knut Eldjarn Collection | |
| Collection of Peter Andresen. | |
| Berge (1993) +1 other reference | |
| Engvoldsen et al. (1991) | |
| Andresen (2013) | |
| Larsen et al. (1981, June) +1 other reference | |
Pakistan | |
| RUFF |
Poland | |
| Evans et al. (2018) |
Russia | |
| Kasatkin et al. (2020) |
| ... |
| European Journal of Mineralogy 19 (2007) |
Sweden | |
| Nysten et al. (2006) |
| Nysten et al. (2006) +1 other reference | |
| Nysten et al. (2006) |
| Öhman et al. (2005) +1 other reference |
USA | |
| Hanley et al. (1950) +1 other reference |
| Eckel et al. (1997) |
| Eckel et al. (1997) | |
| Ream (2004) | |
| Smith (2005) +1 other reference |
| Metamict crystal identified by XRD after annealing at 700° for 48 hours by John Attard et al. (Ce) |
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