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Ferrinatrite

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About FerrinatriteHide

Formula:
Na3Fe(SO4)3 · 3H2O
Colour:
Colourless, grayish white, pale green, bluish green, amethystine; colourless in transmitted light.
Lustre:
Vitreous
Hardness:
Specific Gravity:
2.55 - 2.61
Crystal System:
Trigonal
Name:
From the chemistry of the mineral. FERRIc iron and sodium (NATRium).
This page provides mineralogical data about Ferrinatrite.


Classification of FerrinatriteHide

Approved, 'Grandfathered' (first described prior to 1959)
7.CC.35

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
C : With medium-sized and large cations
29.4.4.1

29 : HYDRATED ACID AND NORMAL SULFATES
4 : AmBn(XO4)p·xH2O, with (m+n):p < 3:2 and > 1:1
25.11.4

25 : Sulphates
11 : Sulphates of Fe and other metals

Physical Properties of FerrinatriteHide

Vitreous
Transparency:
Transparent
Colour:
Colourless, grayish white, pale green, bluish green, amethystine; colourless in transmitted light.
Hardness:
2½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
Perfect on {10_10}
Less perfect {11_20}
Fracture:
Splintery
Density:
2.55 - 2.61 g/cm3 (Measured)    2.55 g/cm3 (Calculated)

Optical Data of FerrinatriteHide

Type:
Uniaxial (+)
RI values:
nω = 1.556 - 1.558 nε = 1.610 - 1.613
Max Birefringence:
δ = 0.054
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Comments:
Colorless in thin section.

Chemical Properties of FerrinatriteHide

Formula:
Na3Fe(SO4)3 · 3H2O
IMA Formula:
Na3Fe3+(SO4)3 · 3H2O

Crystallography of FerrinatriteHide

Crystal System:
Trigonal
Class (H-M):
3 - Rhombohedral
Space Group:
P3
Cell Parameters:
a = 15.553(2) Å, c = 8.6616(17) Å
Ratio:
a:c = 1 : 0.557
Unit Cell V:
1,814.50 ų (Calculated from Unit Cell)
Z:
6
Morphology:
Crystals short prismatic [0001]. Isolated individuals or stellate groups; fibrous aggregates or cleavable masses; cryptocrystalline.

Type Occurrence of FerrinatriteHide

Synonyms of FerrinatriteHide

Other Language Names for FerrinatriteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
3 photos of Ferrinatrite associated with MetavoltineNa6K2FeFe6(SO4)12O2 · 18H2O
1 photo of Ferrinatrite associated with GypsumCaSO4 · 2H2O
1 photo of Ferrinatrite associated with GoldAu
1 photo of Ferrinatrite associated with Halotrichite-Pickeringite Series

Related Minerals - Nickel-Strunz GroupingHide

7.CC.CobaltoblöditeNa2Co(SO4)2•4H2OMon. 2/m : P21/b
7.CC.AndychristyitePbCu2+Te6+O5(H2O)Tric. 1 : P1
7.CC.Ammoniovoltaite(NH4)2Fe2+5Fe3+3Al(SO4)12(H2O)18Iso. m3m (4/m 3 2/m) : Fd3c
7.CC.05KrausiteKFe(SO4)2 · H2OMon. 2/m : P21/m
7.CC.10TamarugiteNaAl(SO4)2 · 6H2OMon. 2/m
7.CC.15KaliniteKAl(SO4)2 · 11H2OMon. 2/m : B2/b
7.CC.15MendoziteNaAl(SO4)2 · 11H2OMon. 2/m
7.CC.20Lonecreekite(NH4)Fe3+(SO4)2 · 12H2OIso.
7.CC.20Alum-(K)KAl(SO4)2 · 12H2OIso. m3 (2/m 3) : Pa3
7.CC.20Alum-(Na)NaAl(SO4)2 · 12H2O
7.CC.20Tschermigite(NH4)Al(SO4)2 · 12H2OIso. m3 (2/m 3) : Pa3
7.CC.20LanmuchangiteTl+Al(SO4)2 · 12H2OIso. m3 (2/m 3) : Pa3
7.CC.25VoltaiteK2Fe2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
7.CC.25ZincovoltaiteK2Zn5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
7.CC.25PertlikiteK2(Fe2+,Mg)2Mg4Fe3+2Al(SO4)12 · 18H2OTet. 4/mmm (4/m 2/m 2/m) : I41/acd
7.CC.25Ammoniomagnesiovoltaite(NH4)2Mg2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
7.CC.30KröhnkiteNa2Cu(SO4)2 · 2H2OMon. 2/m : P21/b
7.CC.40GoldichiteKFe(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.45LöweiteNa12Mg7(SO4)13 · 15H2OTrig.
7.CC.50BlöditeNa2Mg(SO4)2 · 4H2OMon. 2/m
7.CC.50NickelblöditeNa2(Ni,Mg)(SO4)2 · 4H2O
7.CC.50ChangoiteNa2Zn(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.55LeoniteK2Mg(SO4)2 · 4H2OMon. 2/m
7.CC.55MereiteriteK2Fe(SO4)2 · 4H2OMon.
7.CC.60Boussingaultite(NH4)2Mg(SO4)2 · 6H2OMon. 2/m : P21/b
7.CC.60CyanochroiteK2Cu(SO4)2 · 6H2OMon. 2/m
7.CC.60Mohrite(NH4)2Fe(SO4)2 · 6H2OMon. 2/m : P21/b
7.CC.60Nickelboussingaultite(NH4)2Ni(SO4)2 · 6H2O
7.CC.60PicromeriteK2Mg(SO4)2 · 6H2OMon. 2/m
7.CC.65PolyhaliteK2Ca2Mg(SO4)4 · 2H2OTric. 1
7.CC.70LeightoniteK2Ca2Cu(SO4)4 · 2H2OTric.
7.CC.75AmarilliteNaFe(SO4)2 · 6H2OMon. 2/m : B2/b
7.CC.80KonyaiteNa2Mg(SO4)2 · 5H2OMon. 2/m : P21/b
7.CC.85WattevilleiteNa2Ca(SO4)2 · 4H2O (?)Orth.

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

25.11.1NatrojarositeNaFe3(SO4)2(OH)6Trig. 3m : R3m
25.11.2SideronatriteNa2Fe(SO4)2(OH) · 3H2OOrth. 2 2 2 : P21 21 21
25.11.3MetasideronatriteNa2Fe(SO4)2(OH) · H2OOrth. mmm (2/m 2/m 2/m)
25.11.5AmarilliteNaFe(SO4)2 · 6H2OMon. 2/m : B2/b
25.11.6YavapaiiteKFe(SO4)2Mon. 2/m : B2/m
25.11.7KrausiteKFe(SO4)2 · H2OMon. 2/m : P21/m
25.11.8GoldichiteKFe(SO4)2 · 4H2OMon. 2/m : P21/b
25.11.9JarositeKFe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
25.11.10VoltaiteK2Fe2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
25.11.11UngemachiteK3Na8Fe(SO4)6(NO3)2 · 6H2OTrig. 3 : R3
25.11.12MetavoltineNa6K2FeFe6(SO4)12O2 · 18H2OTrig.
25.11.13Sabieite(NH4)Fe3+(SO4)2Trig. 3 2 : P3 2 1
25.11.14Ammoniojarosite(NH4)Fe3+3(SO4)2(OH)6Trig. 3m : R3m
25.11.15Clairite(NH4)2Fe3(SO4)4(OH)3 · 3H2OTric.
25.11.16Mohrite(NH4)2Fe(SO4)2 · 6H2OMon. 2/m : P21/b
25.11.17Lonecreekite(NH4)Fe3+(SO4)2 · 12H2OIso.
25.11.18Godovikovite(NH4)Al(SO4)2Trig. 3 2 : P3 2 1
25.11.19BotryogenMgFe3+(SO4)2(OH) · 7H2OMon. 2/m
25.11.21Slavíkite(H3O+)3Mg6Fe15(SO4)21(OH)18 · 98H2OTrig. 3 : R3
25.11.23SturmaniteCa6(Fe3+,Al,Mn3+)2(SO4)2[B(OH)4](OH)12 · 25H2OTrig. 3m : P3 1c
25.11.24Millosevichite(Al,Fe)2(SO4)3Trig. 3 : R3
25.11.25AluminocopiapiteAl2/3Fe3+4(SO4)6(OH)2 · 20H2OTric. 1 : P1
25.11.26HalotrichiteFeAl2(SO4)4 · 22H2OMon. 2 : P2
25.11.27Idrizite(Mg,Fe)(Al,Fe)2(SO4)3(OH)2 · 15H2O or near
25.11.28LishizheniteZnFe2(SO4)4 · 14H2OTric. 1 : P1
25.11.29ZincovoltaiteK2Zn5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c

Other InformationHide

Notes:
Alters to sideronatrite in moist air.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for FerrinatriteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Mackintosh (1889) American Journal of Science [3]: 38: 244 (as ferromatrite).
Frenzel (1890) Mineralogische und petrographische Mitteilungen, Vienna: 11: 218.
Genth and Penfield (1890) American Journal of Science: 40: 202.
Arzruni and Frenzel (1891).
Scharizer (1906) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 41: 210.
Ungemach (1935) Bulletin de la Société française de Minéralogie: 58: 203 (as Leucoglaucite)
Bandy (1938) American Mineralogist: 23: 731.
Gordon (1942) Not. Nat., Academy of Sciences, Philadelphia, no.103.
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 456-457.
Scordari, F. (1977): The crystal structure of ferrinatrite, Na3(H2O)3[Fe(SO4)3] and its relationship to Maus's salt, (H3O)2K2{K0.5(H2O)0.5}6[Fe3O(H2O)3(SO4)6](OH)2. Mineralogical Magazine 41, 375-383.
Yang, Z., & Giester, G. (2019). Structure refinement and hydrogen bonding of ferrinatrite, Na 3 Fe (SO 4) 3⋅ 3H 2 O. Mineralogy and Petrology, 1-8.
Handbook of Mineralogy: Vol V: 223.

Internet Links for FerrinatriteHide

Localities for FerrinatriteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Argentina
 
  • Jujuy Province
    • Santa Bárbara Department
      • Cerros de Santa Bárbara (Cerro Santa Bárbara)
        • El Palmar hot springs
Zavalia, Maria Florencia Marquez & Galliski, Miguel Angel (1995): Goldichite of fumarolic origin from the Santa Barbara mine, Jujuy, northwestern Argentina. Canadian Mineralogist 33, 1059-1062.
Chile
 
  • Antofagasta
    • Antofagasta Province
      • Mejillones
        • Mejillones peninsula
SEM-EDS and XRD by Igor V. Pekov
XRD by Joachim Lorenz
      • Sierra Gorda
NJMM (1987), 171; Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 457, 605, 620.
    • El Loa Province
      • Calama
        • Cerritos Bayos
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. 7th edition: 457.; Kampf, A.R.; Mills, S.J.; Housley, R.M.; Williams, P.A.; Dini, M. (2012): Alcaparrosaite, K3Ti4+Fe3+(SO4)4O(H2O)2, a new hydrophobic Ti4+ sulfate from Alcaparrosa, Chile. Mineralogical Magazine 76, 851-861.
        • Chuquicamata District
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 457.
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 457.
  • Atacama
    • Copiapó Province
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 457.
  • Tarapacá
    • Iquique Province
      • Salar Grande
Wet Chemical by Gerhard Möhn
China
 
  • Xinjiang
    • Hami Prefecture (Kumul Prefecture; Qumul Prefecture)
      • Yizhou District
Yang, Z., & Giester, G. (2019). Structure refinement and hydrogen bonding of ferrinatrite, Na 3 Fe (SO 4) 3⋅ 3H 2 O. Mineralogy and Petrology, 1-8.
Costa Rica
 
  • Cartago Province
    • Irazú Volcano
Ulloa, A., Gázquez, F., Sanz Arranz, A., Medina García, J., Rull Pérez, F., Calaforra, J. M., ... & De Waele, J. (2018). Extremely high diversity of sulfate minerals in caves of the Irazú Volcano (Costa Rica) related to crater lake and fumarolic activity.
Germany
 
  • North Rhine-Westphalia
    • Arnsberg
      • Hochsauerlandkreis
        • Marsberg
Lapis, 16 (12), 13-21+58.
        • Meschede
Schnorrer-Köhler, G., (1988): Mineralogische Notizen IV, Der Aufschluss, Vol. 39, 153-168
    • The Ruhr
      • Herne
No reference listed
  • Saxony
    • Dresden
Thalheim, K.; Reichel, W. & Witzke, T. (1991): Die Minerale des Döhlener Beckens.- Schriften des Staatlichen Museums für Mineralogie und Geologie zu Dresden, Nr. 3
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Lavrion District Mines
          • Agios Konstantinos [St Constantine] (Kamariza)
            • Kamariza Mines (Kamareza Mines)
              • Hilarion area
Rieck, B., Kolitsch, U., Voudouris, P., Giester, G. and Tzeferis, P. (2018): Weitere Neufunde aus Lavrion, Griechenland. Mineralien-Welt 29 (5), 32-77 (in German).
          • Sounion area
            • Sounion Mines
Rieck, B., Kolitsch, U., Voudouris, P., Giester, G. and Tzeferis, P. (2018): Weitere Neufunde aus Lavrion, Griechenland. Mineralien-Welt 29 (5), 32-77 (in German).
Italy
 
  • Campania
    • Naples
      • Somma-Vesuvius Complex
Russo, M., Punzo, I. (2004): I minerali del Somma-Vesuvio, AMI
  • Sicily
    • Messina Province
      • Eolie Islands (Aeolian Islands)
        • Lipari
          • Vulcano Island
Campostrini, I., Demartin, F., Gramaccioli, C.M., Russo, M. (2011): Vulcano - Tre secoli di mineralogia. AMI-Associazione Micromineralogica Italiana, Cremona, Italy, 344 pp.
  • Tuscany
    • Siena Province
      • Chiusdino
Mineralogical Record, 15 (1), 27-36.; Menchetti, S., Batoni, M., Batacchi, C., Borselli, G., Brogi, A., Ceccantini, L., Fassina, B., Marchesini, M., Rossellini, A. & Ruggieri, G. (2015): Le Cetine di Cotorniano. Miniera e minerali. Associazione Micro-Mineralogica Italiana, Cremona, 354 p.
Lebanon
 
  • South Governate
    • Jezzine District
Kruszewski, Ł., 2018/2019. Secondary sulfate minerals from Bhanine valley coals (South Lebanon) – a crystallochemical and geochemical study. Geological Quarterly (in press)
Poland
 
  • Silesian Voivodeship
    • Rybnik Co.
      • Gmina Czerwionka-Leszczyny
Parafiniuk, J. and Kruszewski, Ł. (2009): Ammonium minerals from burning coal-dumps of the Upper Silesian Coal Basin (Poland). Geol. Quart., 53, 341-356. http://www.pgi.gov.pl/images/stories/G_Q/53_3/parafiniuk.pdf]
USA
 
  • Utah
    • San Juan Co.
      • Red Canyon
Plášil, j.,Kampf, A.R., Kasatkin, A.V., Marty, J., Škoda, R., Silva, S. & Čejka, J. (2013): Meisserite, Na5(UO2)(SO4)3(SO3OH)(H2O), a new uranyl sulfate mineral from the Blue Lizard mine, San Juan County, Utah, USA. Mineralogical Magazine. 77, 2975-2988.
  • Virginia
    • Louisa Co.
      • Gold-Pyrite Belt
        • Mineral
Minerals of Virginia, 1990 by R. V. Dietrich
    • Wise Co.
      • Big Stone Gap
Minerals of Virginia, 1990 by R. V. Dietrich
Minerals of Virginia, 1990 by R. V. Dietrich
Uzbekistan
 
  • Fergana Region
    • Uzbekistan District
Uklonskiy, A.S. [Уклонский, А.С.] (1964) Geochemistry of native sulphur [К геохимии самородной серы]. Uzbek Geological Journal [Uzbekskiy Geologicheskiy Zhurnal, Узбекский геологический журнал], 6, 5-10; Uklonskiy, A.S. [Уклонский, А.С.] (1982) Geochemistry of native sulphur [К геохимии самородной серы]. In: Problems of mineralogy and geochemistry. Selected papers [Проблемы минералогии и геохимии. Избранные труды]. Uzbek SSR Branch, Academy of Sciences Press [Издательство "Фан" Узбекской ССР], Tashkent, 66-71.
 
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