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Cuprobismutite

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About CuprobismutiteHide

Formula:
Cu8AgBi13S24
Colour:
Dark bluish-grey
Lustre:
Metallic
Specific Gravity:
6.36
Crystal System:
Monoclinic
Name:
In allusion to its content of copper and bismuth.
Structurally closely related to hodrušite and kupčíkite.

Compare, e.g., UM1991-11-S:AgBiCu.


Classification of CuprobismutiteHide

Approved, 'Grandfathered' (first described prior to 1959)
2.JA.10a

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
J : Sulfosalts of PbS archetype
A : Galena derivatives with little or no Pb
3.8.2.1

3 : SULFOSALTS
8 : 1 < ø < 2
5.1.8

5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
1 : Sulpharsenites etc. of Cu

Physical Properties of CuprobismutiteHide

Metallic
Transparency:
Opaque
Colour:
Dark bluish-grey
Density:
6.36 g/cm3 (Measured)    6.24 g/cm3 (Calculated)

Optical Data of CuprobismutiteHide

Type:
Anisotropic
Anisotropism:
Distinct

Chemical Properties of CuprobismutiteHide

Formula:
Cu8AgBi13S24

Crystallography of CuprobismutiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
C2/m
Cell Parameters:
a = 17.520(1) Å, b = 3.926(3) Å, c = 15.261(1) Å
β = 100.18(1)°
Ratio:
a:b:c = 4.463 : 1 : 3.887
Unit Cell V:
1,033.18 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Massive, prismatic crystals, thin blades

Geological EnvironmentHide

Geological Setting:
Quartz veins

Type Occurrence of CuprobismutiteHide

Other Language Names for CuprobismutiteHide

Simplified Chinese:辉铜铋矿
Traditional Chinese:輝鉍銅礦

Relationship of Cuprobismutite to other SpeciesHide

Other Members of this group:
HodrušiteCu8Bi12S22Mon.
KupčíkiteCu3.4Fe0.6Bi5S10Mon. 2/m : B2/m

Common AssociatesHide

AikinitePbCuBiS3
BenjaminiteAg3Bi7S12
BerryiteCu3Ag2Pb3Bi7S16
CupropavoniteCu0.9Ag0.5Pb0.6Bi2.5S5
EmplectiteCuBiS2
WitticheniteCu3BiS3
Associated Minerals Based on Photo Data:
1 photo of Cuprobismutite associated with AnglesitePbSO4
1 photo of Cuprobismutite associated with Feldspar Group
1 photo of Cuprobismutite associated with CannoniteBi2(SO4)O(OH)2
1 photo of Cuprobismutite associated with BismuthiniteBi2S3

Related Minerals - Nickel-Strunz GroupingHide

2.JA.05eBenjaminiteAg3Bi7S12Mon. 2/m : B2/m
2.JA.05gBorodaeviteAg5(Bi,Pb,Fe)8(Sb,Bi)2S17Mon.
2.JA.05aCupropavoniteCu0.9Ag0.5Pb0.6Bi2.5S5Mon. 2/m : B2/m
2.JA.05aKitaibeliteAg10PbBi30S51
2.JA.05iLivingstoniteHgSb4S6(S2)Mon. 2/m : B2/b
2.JA.05dMakovickyiteCu1.12Ag0.81Pb0.27Bi5.35S9Mon. 2/m
2.JA.05fMummeiteCu0.58Ag3.11Pb1.10Bi6.65S13Mon.
2.JA.05aPavoniteAgBi3S5Mon. 2/m : B2/m
2.JA.05bGrumipluciteHgBi2S4Mon. 2/m : B2/m
2.JA.05hMozgovaitePbBi4S7Orth.
2.JA.05dCupromakovickyiteCu4AgPb2Bi9S18Mon. 2/m : B2/m
2.JA.05cKudriavite(Cd,Pb)Bi2S4Mon. 2/m : B2/m
2.JA.05aCupromakopavoniteAg3Cu8Pb4Bi19S38Mon. 2/m : B2/m
2.JA.05DantopaiteAg5Bi13S22Mon. 2/m : B2/m
2.JA.10cHodrušiteCu8Bi12S22Mon.
2.JA.10ePadĕraiteCu7[(Cu,Ag)0.33Pb1.33Bi11.33]S22Mon.
2.JA.10dPizgrischite(Cu,Fe)Cu14PbBi17S35Mon. 2/m : B2/m
2.JA.10bKupčíkiteCu3.4Fe0.6Bi5S10Mon. 2/m : B2/m
2.JA.15SchapbachiteAg0.4Pb0.2Bi0.4SIso.
2.JA.15CuboargyriteAgSbS2Iso. m3m (4/m 3 2/m)
2.JA.20BohdanowicziteAgBiSe2Trig. 3m (3 2/m) : P3m1
2.JA.20MatilditeAgBiS2Trig. 3m (3 2/m) : P3m1
2.JA.20VolynskiteAgBiTe2Orth.

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

5.1.1SinneriteCu6As4S9Tric. 1 : P1
5.1.2TennantiteCu6(Cu4X2)As4S12SIso. 4 3m : I4 3m
5.1.4ChalcostibiteCuSbS2Orth. mmm (2/m 2/m 2/m)
5.1.5TetrahedriteCu6(Cu4X2)Sb4S13Iso. 4 3m : I4 3m
5.1.6Goldfieldite(Cu102)Te4S12SIso. 4 3m : I4 3m
5.1.7EmplectiteCuBiS2Orth. mmm (2/m 2/m 2/m) : Pmna
5.1.9WitticheniteCu3BiS3Orth. 2 2 2 : P21 21 21
5.1.10HodrušiteCu8Bi12S22Mon.
5.1.11GirauditeCu6Cu4(Fe2+,Zn)2As4Se12SIso. 4 3m : I4 3m
5.1.11PermingeatiteCu3SbSe4Tet.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for CuprobismutiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Hillebrand (1884) American Journal of Science: 27: 355.
Dana (1892): 110.
Palache, Charles, Harry Berman & Clifford Frondel (1944), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana Yale University 1837-1892, Volume I: Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, Inc., New York. 7th edition, revised and enlarged: 437.
American Mineralogist (1952): 37: 447-452.
American Mineralogist (1973): 58: 967.
Topa, D., Makovicky, E. & Balić-Žunić, T. (2003): Crystal structures and crystal chemistry of members of the cuprobismutite homologous series of sulfosalts: Canadian Mineralogist 41, 1481-1501. [cuprobismutite, hodrushite]
Cook, N. J. & Ciobanu, C. L. (2003): Lamellar minerals of the cuprobismutite series and related paděraite: A new occurrence and implications. Can. Mineral., 41, 441-456. ["Ag appears to be an essential component of cuprobismutite"]
Ciobanu, C. L.; Pring, A.; Cook, N. J. (2004): Micron- to nano-scale intergrowths among members of the cuprobismutite series and paderaite: HRTEM and microanalytical evidence. Mineralogical Magazine 68, 279-300.
Journal of Research, US Geological Survey: 1: 99-103.
Pieczka, A. & Golebiowska, B. (2012): Cuprobismutite homologues in granitic pegmatites from Szklarska Poreba, Karkonosze Massif, southwestern Poland. Canadian Mineralogist 50, 313-324.

Internet Links for CuprobismutiteHide

Localities for CuprobismutiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Argentina
 
  • Catamarca Province
    • Andalgalá Department
Hubert, P., Werner, H., & Dan, T. (2009). A contribution to the knowledge of the mineralization at Mina Capillitas, Catamarca. Revista de la Asociacion Geologica Argentina, 64(3), 514-524.
  • Chubut Province
    • Futaleufú department
      • Los Cipreses
Brodtkorb, Milka K. de (2002) Las Especies Minerales de la República Argentina. Tomo I. (Asociación Mineralógica Argentina)
Australia
 
  • Northern Territory
    • Barkly Region
      • Tennant Creek
Skirrow, R.G. (1993) The genesis of gold-copper-bismuth deposits, Tennant Creek, Northern Territory, PhD thesis (unpublished) Australian National University.
Austria
 
  • Salzburg
    • Zell am See District
      • Mittersill
        • Mittersill Scheelite deposit
Lapis 29(5):42 (2004)
Bolivia
 
Royal Ontario Museum specimen # M13339
    • Larecaja Province
      • Sorata
Royal Ontario Museum specimen # M13339
Bulgaria
 
  • Burgas Province
    • Malko Tarnovo
Cook, N. J., Ciobanu, C. L., & Bogdanov, K. (2002) Trace mineralogy of the Upper Cretaceous banatitic Magmatic and metallogenetic Belt, SE Europe. In 11th Quadrennial IAGOD symposium–Geocongress 2002, Windhoek, Namibia, July 2002. CD Volume of extended abstracts.
    • Sozopol
Cook, N. J., Ciobanu, C. L., & Bogdanov, K. (2002) Trace mineralogy of the Upper Cretaceous banatitic Magmatic and metallogenetic Belt, SE Europe. In 11th Quadrennial IAGOD symposium–Geocongress 2002, Windhoek, Namibia, July 2002. CD Volume of extended abstracts.
Canada
 
  • British Columbia
    • Omenica Mining Division
      • Owen Lake
Hood, C. T., Sinclair, A. J., & Leitch, C. H. (1991). British Columbia Geological Survey Geological Fieldwork 1991.
China
 
  • Yunnan
    • Chuxiong
      • Yao'an County
Zhou, H., Sun, X., Wu, Z., Yang, T., Li, D., Ren, Y., Liu, Q., Zhu, K. & Yu, H. (2018). Mineralogy of Bi-sulfosalts and tellurides from the Yaoan gold deposit, southwest China: metallogenic implications. Ore Geology Reviews 98, 126-140.
Czech Republic
 
  • Ústí nad Labem Region
Anthony, Bideaux, Bladh, Nichols: "Handbook of Mineralogy", Vol. 1, 1990
France
 
  • Corsica
    • Corse-du-Sud
      • Testa
Lheur, C., Meisser,N., Pecorini, R. and Steinmetz, A. (2011): Nouveautés minéralogiques en Corse. La Régne Minéral. 102: 33-40
  • Grand Est
    • Haut-Rhin
      • Colmar-Ribeauvillé
Wittern, Journée: "Mineralien finden in den Vogesen", von Loga (Cologne), 1997
P&T N°23-24, H. BARI 1982, Minéralogie des filons du Neuenberg à Sainte Marie aux Mines (Haut-Rhin).
            • Sankt Johann vein
Ruhlmann, F. (1978): The bismuth paragenesis in the veins of the Engelsbourg mine (Sainte-​Marie-​aux-​Mines district, Vosges, France). Bulletin de Minéralogie 101(5-6), 570-572 (in French).
  • Provence-Alpes-Côte d'Azur
    • Alpes-Maritimes
      • Saint-Etienne-de-Tinée
R. Pierrot, P. Picot, J. Feraud, J. Vernet : "Inventaire Minéralogique de la France, N° 4, Alpes Maritimes", BRGM, 1974
Germany
 
  • Baden-Württemberg
    • Freiburg
      • Ortenaukreis
Lapis 1984(1), 41-42
        • Oberwolfach
Walenta, K. (1992): Die Mineralien des Schwarzwaldes. Chr. Weise Verlag, München, 336 pp. (in German)
    • Schapbach
      • Wildschapbach valley
Wittern: "Mineralfundorte in Deutschland", 2001
  • Bavaria
    • Lower Franconia
      • Aschaffenburg
        • Waldaschaff
Lorenz, J., Schmitt, R., Hahn, W. (2007): Rhabdophan und Cuprobismutit von der Barytgrube "Pauline" in Waldaschaff im Spessart, Der Aufschluss, Vol. 58, 41-54
    • Upper Palatinate
      • Neustadt an der Waldnaab
        • Waidhaus
          • Hagendorf
http://www.berthold-weber.de/h_miner.htm
  • Rhineland-Palatinate
    • Altenkirchen
      • Betzdorf-Gebhardshain
        • Schutzbach
Weiss: "Mineralfundstellen, Deutschland West", Weise (Munich), 1990
Indonesia
 
  • South Sulawesi Province
    • Gowa Regency
Nur, I., Idrus, A., Pramumijoyo, S., Harijoko, A., Watanabe, K., Imai, A., ... & Irfan, U. R. (2012). Elemental Mass Balance of the Hydrothermal Alteration Associated with the Baturappe Epithermal Silver-Base Metal Prospect, South Sulawesi, Indonesia.
Japan
 
  • Yamagata Prefecture
Izumino, Y., Nakashima, K., & Nagashima, M. (2014). Cuprobismutite group minerals (cuprobismutite, hodrušhite, kupčíkite and padĕraite), other Bi–sulfosalts and Bi–tellurides from the Obari mine, Yamagata Prefecture, Japan. Journal of Mineralogical and Petrological Sciences, 109(4), 177-190.
Morocco
 
  • Drâa-Tafilalet Region
S. Weiß: Lapis 31(7/8), 72-73 (2006)
Peru
 
  • Pasco
    • Pasco Province
      • Simón Bolívar District
Baumgartner, R. et al. (2008): Economic Geology 103, 493-537
Poland
 
  • Lower Silesian Voivodeship
    • Jelenia Góra County
      • Szklarska Poręba
        • Szklarska Poręba-Huta
Pieczka, A. & Golebiowska, B. (2012): Cuprobismutite homologues in granitic pegmatites from Szklarska Poręba, Karkonosze Massif, southwestern Poland. Canadian Mineralogist 50, 313-324.; Pieczka, A., & Gołębiowska, B. (2012). Cuprobismutite homologues in granitic pegmatites from Szklarska Poręba, Karkonosze massif, southwestern Poland. The Canadian Mineralogist, 50(2), 313-324.; Kozłowski, A., & Matyszczak, W. (2018). Oxygenic bismuth minerals in the NE part of the Karkonosze pluton (West Sudetes, SW Poland). Acta Geologica Polonica, 68(4).; Mochnacka, K., Oberc-Dziedzic, T., Mayer, W., & Pieczka, A. (2015). Ore mineralization related to geological evolution of the Karkonosze–Izera Massif (the Sudetes, Poland)—Towards a model. Ore Geology Reviews, 64, 215-238.
  • Silesian Voivodeship
    • Myszków County
      • Kraków-Lubliniec tectonic zone
        • Żarki-Kotowice area
Karwowski, Ł., Markowiak, M. (2012): Polymetallic mineralization in Ediacaran sediments in the Żarki-Kotowice area, Poland. Mineralogia: 43(3-4), 199-212
Portugal
 
  • Évora
    • Vila Viçosa
      • Conceição
Gustavo Pereira Fernandes, Mineralizações de Cobre da Mina de Miguel Vacas: Caracterização Petrográfica e Geoquímica, Universidade de Lisboa, Faculdade de Ciências, Departamento de Geologia, 2012
Romania
 
  • Bihor
    • Nucet
www.minerals-of-the carpathians.eu (2009); Cook, N. J., Ciobanu, C. L., & Bogdanov, K. (2002) Trace mineralogy of the Upper Cretaceous banatitic Magmatic and metallogenetic Belt, SE Europe. In 11th Quadrennial IAGOD symposium–Geocongress 2002, Windhoek, Namibia, July 2002. CD Volume of extended abstracts.
Shimizu, M., Kato, A., Cioflica, G., Lupulescu, M., Shimizu, M. (1998): Friedrichite from Băița Bihor, Romania. Canadian Mineralogist 36, 861-868.
Shimizu, M., Kato, A., Cioflica, G., Lupulescu, M., Shimizu, M. (1998): Friedrichite from Băița Bihor, Romania. Canadian Mineralogist 36, 861-868.
Shimizu, M., Kato, A., Cioflica, G., Lupulescu, M., Shimizu, M. (1998): Friedrichite from Băița Bihor, Romania. Canadian Mineralogist 36, 861-868.
  • Caraş-Severin
    • Banat Mountains
Cook, N. J., Ciobanu, C. L., & Bogdanov, K. (2002) Trace mineralogy of the Upper Cretaceous banatitic Magmatic and metallogenetic Belt, SE Europe. In 11th Quadrennial IAGOD symposium–Geocongress 2002, Windhoek, Namibia, July 2002. CD Volume of extended abstracts.
        • Ocna de Fier (Vaskö-Moraviţa; Vaskö-Moravicza; Eisenstein)
Cook, N. J. & Ciobanu, C. L. (2003): Lamellar minerals of the cuprobismutite series and related paděraite: A new occurrence and implications. Can. Mineral., 41, 441-456; Ciobanu, C. L.; Pring, A.; Cook, N. J. (2004): Micron- to nano-scale intergrowths among members of the cuprobismutite series and paderaite: HRTEM and microanalytical evidence. Mineralogical Magazine 68, 279-300.
Russia
 
  • Altai Republic
    • Kosh-Agachsky District
Potseluev, A.A., Babkin, D.I., and Kotegov, V.I. (2006): Geology of Ore Deposits 48(5), 384-401.
Slovakia
 
  • Banská Bystrica Region
    • Žarnovica District
      • Hodruša-Hámre (Hodritsch)
Jeleň, S., Pršek, J., Kovalenker, V. A., Topa, D., Sejkora, J., Števko, M., & Ozdín, D. (2012). Bismuth Sulfosalts Of The Cuprobismutite, Pavonite And Aikinite Series From The Rozália Mine, Hodruša–Hámre, Slovakia. The Canadian Mineralogist, 50(2), 325-340.
  • Košice Region
    • Rožňava Co.
Koděra, M. et al., 1986 a 1990 : Topografická mineralógia Slovenska, diel 1- 3, Veda – Vydavateľstvo SAV, Bratislava, 1990, 1 – 1590k
  • Trenčín Region
    • Bánovce nad Bebravou District
      • Čierna Lehota
Mikuš T., 2001: Mineralógia rudných výskytov v Malej Magure a Suchom (dipl.práca), archív Kated.miner. a peňtr. PFUK, Bratislava, 128 s; Mikuš, T., Chovan, M., Ponomarenko, O., Bondarenko, S., & Grinchenko, O. (2013). Hydrothermal Nickel Mineralization from the Black Shales in Čierna Lehota. Мінералогічний журнал, (35,№ 3), 27-32.; Jeleň, S., Mikuš, T., & Pršek, J. (2009). Sulphosalts of cuprobismutite homologous series from Banská Hodruša and Čierna Lehota (Western Carpathians, Slovakia). Мінералогічний збірник, (2), 64-76.
Switzerland
 
  • Valais
    • Anniviers Valley
      • Ayer
Ansermet, S. (2012): Mines et minéraux du Valais - II. Anniviers et Tourtemagne. With contributions by N. Meisser, Ed. Porte-plumes (Ayer)
      • Grimentz
Picot, P. and Johan, Z. (1977). Atlas des Minéraux Métalliques, BRGM, Elsevier
    • Evionnaz
      • Salanfe
Meisser, N. (2012): La minéralogie de l'uranium dans le massif des Aiguilles Rouges. Matér. Géol. Suisse, Sér. géotech. 96, 183 p.
USA
 
  • California
    • Mono Co.
      • Bodie Hills
        • Masonic Mining District
          • New York Hill
MarekC pers. coll. 2017-2018
  • Colorado
    • Custer Co.
      • Rosita Mining District
Minerals of Colorado (1997) Eckel, E. B.
    • Park Co.
      • Montezuma Mining District
        • Hall Valley (Hall's Valley)
Amer.J.Sci.(1884) ser. 3, 27, 349-358 (p. 355); U.S. Geological Survey Professional Paper 223
    • Summit Co.
USGS PP 223(Lovering,1950)
  • Connecticut
    • Middlesex Co.
      • Portland
Vajdak, Josef. (1997), New Mineral Finds in 1996, News from Vajdak of Pequa Rare Minerals and Metals. Mineral News: 13:(3): 1,4,5.
  • Utah
UGMS Bull 117 Minerals and Mineral Localities of Utah
    • Piute Co.
      • Bullion Canyon
        • Ohio Mining District
UGMS Bull 117 Minerals and Mineral Localities of Utah; Stanley C J, Roberts A C, Harris D C, Criddle A J, Szymanski J T (1992) Cannonite, Bi2O(OH)2SO4, a new mineral from Marysvale, Utah, USA. Mineralogical Magazine 56, 605-609.
      • Cottonwood Creek
        • Mount Baldy Mining District
Econ Geol (1986) 81:1932-1952
  • Virginia
    • Fairfax Co.
      • Culpeper Basin
        • Centreville
Minerals of Virginia, 1990 by R. V. Dietrich
 
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