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Buserite from
Pinal Creek, Globe Placers, Globe, Globe Hills Mining District, Globe-Miami Mining District, Gila County, Arizona, USA


Locality type:Creek
Classification
Species:'Buserite' (not an IMA approved species)
Formula:Na4Mn14O27 · 21H2O
Confirmation
Validity:Believed Valid
Data
Mineral Data:Click here to view Buserite data
Locality Data:Click here to view Pinal Creek, Globe Placers, Globe, Globe Hills Mining District, Globe-Miami Mining District, Gila County, Arizona, USA
Data Identifiers
Mindat Occurrence Record ID:354240
Long-form Identifier:1:3:354240:8
GUID (UUID V4):a1ac3e47-7a49-442c-9bf1-0ea706d1c2d8
References
Reference Search (possible matching items)
Journal (article/letter/editorial)
oxides in cemented streambed crusts from Pinal Creek, Arizona, U.S.A., and in hot-spring deposits from...precipitated terrestrial Mn oxides from Pinal Creek (Arizona, U.S.A.) and from Yuno-Taki Falls (Hokkaido...found not to be very useful in distinguishing buserite and birnessite, but a distinct pattern was observed...ideal buserite with an XRD pattern similar to synthetic samples. An older, non-ideal buserite could be...Mössbauer spectroscopy. A test of the possibility of buserite transformation showed that autoclaving a sample
Journal (article/letter/editorial)
characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ John R. Bargar a,*, Christopher C. Fuller...Road, Building 137, MS 69, Menlo Park, CA 94025, USA b US Geological Survey, Water Resources Division...345 Middlefield Road, MS 465, Menlo Park, CA 94025, USA c Advanced Light Source, Lawrence Berkeley National...Laboratory, One Cyclotron Road, Berkeley, CA 94720, USA d Department of Earth and Planetary Sciences, MSC03-2040...University of New Mexico, Albuquerque, NM 87131, USA Received 19 March 2008; accepted in revised form
Journal (article/letter/editorial)
d-spacing (lithiophorite; 10 Å manganate; or buserite, not an official mineral but structurally related...sometimes distinguishes 10 Å phyllomanganates (i.e., buserite) from tunnel manganates (i.e., todorokite), which...Netherlands Water column of stratified lake, MI, USA Lab studies (Tournassat et al. 2002) Lab studies...secondary product is the hydrated phyllomanganate buserite, characterized by d-spacings of 10.1–10.2 Å....manganate resembling buserite was formed in buffer, whereas a mixture of buserite and a Mg-rich noncollapsible
Journal (article/letter/editorial)
Copyright © 2003 Elsevier Science Ltd Printed in the USA. All rights reserved 0016-7037/03 $30.00 ⫹ .00 Pergamon...94720-3110, USA Stanford Synchrotron Radiation Laboratory, SLAC, P.O Box 4349, Stanford, CA 94309, USA (Received...bacteria) in the hyporheic zone connecting Pinal Creek (Arizona, USA) to a shallow groundwater plume. The Mn...oxides: todorokite, birnessite group minerals, and “buserite” [an informal name given to a hydrated layer type...the layer type Mn(III, IV) oxides, birnessite, “buserite,” and vernadite, along with the tunnel-structured
Journal (article/letter/editorial)
the birnessite may initially be identified as buserite, the hydrated relative of birnessite that has...has a distinct ~10 Å spacing. Upon heating buserite to 110 °C, the 10 Å spacing collapses as interlayer...PBS-M2f-2) exhibited a 10 Å basal d-spacing, indicating buserite-like structures (Supplemental1 Fig. S4); these...Co2+ cations have been observed to stabilize the buserite structure, and both Ca2+ and Mg2+ were detected...The central Pennsylvanian DS1-M3f sample, also a buserite, somewhat resembled triclinic birnessite initially
Journal (article/letter/editorial)
oxides in cemented streambed crusts from Pinal Creek, Arizona, U.S.A., and in hot-spring deposits from...Dixon, J.B. (1987) Transformation of birnessite to buserite, todorokite, and manganite under mild hydrothermal...manganese oxide forming sediment in Pinal Creek, Globe Mining District, Arizona. Environmental Science and Technology...mechanism of formation from Na-rich monoclinic buserite at low pH. American Mineralogist, 85, 826–838...Doubleaging method for preparation of stabilized Na-buserite and transformations to todorokites incorporated
Journal (article/letter/editorial)
94720, USA b Earth Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA c Stanford...Synchrotron Radiation Lightsource, Menlo Park, CA 94025, USA d STFC Rutherford Appleton Laboratory, Didcot, Oxfordshire...samples from Pinal Creek, Arizona, an aquatic ecosystem adversely impacted by copper mining (Fuller and... 37 Mulford Hall #3114 Berkeley, CA 94720-3114, USA. Tel.: +1 510 643 9951; fax: +1 510 643 2940. E-mail...characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ. Geochim. Cosmochim. Acta 73, 889–910. Bodei
Journal (article/letter/editorial)
Cambridge, MA, USA b Stanford Synchrotron Radiation Lightsource, Menlo Park, CA, USA c Environmental...Pacific Northwest National Laboratory, Richland, WA, USA Received 14 September 2010; accepted in revised form...Applied Sciences, 29 Oxford St., Cambridge, MA 02138, USA. Fax: +1 617 496 1471. E-mail address: hansel@seas...10th and Constitution Ave., Washington, DC 20560, USA. 0016-7037/$ - see front matter Ó 2011 Elsevier...characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ. Geochim. Cosmochim. Acta 73, 889–910. Bargar
Journal (article/letter/editorial)
Berkeley National Laboratory, Berkeley, CA 94720, USA Computational Science and Engineering Department...characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ. Geochim. Cosmochim. Acta 73, 889–910. Burns...manganese oxide forming sediment in Pinal Creek, globe mining district, Arizona. Environ. Sci. Technol. 35, 4719–4725...mechanism of Co2+ oxidation by the phyllomanganate buserite. Am. Mineral. 82, 1150–1175. Manceau A., Lanson...environmental significance. Proc. Natl. Acad. Sci. USA 96, 3447–3454. Shannon R. D. (1976) Revised effective
Journal (article/letter/editorial)
oxidation state, the 23Na NMR spectra of metastable buserite and two birnessite samples, NaBi-H-I and NaBi-II...these materials. The small 23Na chemical shift of buserite shows that its interlayer sodium is fully hydrated...metastable intermediate phase commonly referred to as buserite (Feng et al. 2000) containing extra interlayer...10 Å. By acidifying a suspension of metastable buserite, one can also form a hexagonal birnessite, for...rationalize the 23Na NMR spectra of the synthetic sodium buserite and birnessite samples investigated in this study
Journal (article/letter/editorial)
the San Diego River Watershed, Southern California USA Eleanora I. Robbins 1, *, Shannon Quigley-Raymond...University, 5500 Campanile Dr., San Diego, CA 92182-1020, USA The San Diego River Park Foundation, 4891 Pacific...Pacific Highway, Suite 114, San Diego, CA 92110, USA; shannon@sandiegoriver.org City of San Diego, Storm Water...Diego, CA 92123, USA; MLai@sandiego.gov 3826 Elkhorn Blvd., North Highlands, CA 95660, USA; janaefried@yahoo...the sparsely developed headwaters, the Temescal Creek tributary emerges from pyrite-bearing metamorphic
Journal (article/letter/editorial)
sequestration of Ni in Mn oxides. Keywords: nickel; buserite; asbolane; todorokite; Mn oxides 1. INTRODUCTION...presence of two planes of interlayer water molecules (buserite), as reported by Manceau et al. (2007b). At high...2 Å (birnessite or vernadite) to ≈9.4-10.2 Å (buserite, asbolane, and lithiophorite – Burns et al., 1983;...Co (Wu et al., 2019). As described above, buserite-, lithiophorite-, and asbolane-like phyllomanganates...responsible for the transformation of birnessite/buserite to todorokite or asbolane are inferred. 2. MATERIALS
Journal (article/letter/editorial)
manganese oxide forming sediment in Pinal Creek, globe mining district, Arizona. Environmental Science and Technology...mechanism of Co2+ oxidation by the phyllomanganate buserite. American Mineralogist 82, 1150–1175. Manceau
Journal (article/letter/editorial)
19716, USA b Delaware Environmental Institute, University of Delaware, Newark, DE 19716, USA c Department...Hall, University of Delaware, Newark, DE 19716, USA Received 15 May 2009; accepted in revised form 3...Hall, University of Delaware, Newark, DE 19716, USA. Tel.: +1 302 831 6378; fax: +1 302 831 0605. E-mail... The University of California, Davis, CA 95616, USA. 0016-7037/$ - see front matter Ó 2010 Elsevier...XRD patterns of biogenic Mn oxide, vernadite, buserite and todorokite are often indistinguishable and
Journal (article/letter/editorial)
Company in Olomouc (Schieferbergbau AG Olmütz). Slate mining at the place reached yearly production 36000 m2...accompany alumogel and ferrihydrite. Most common is buserite-Ca with an average formula Ca1.75Mg0.32Na0.02Ni0...oxygens, and moisture-free base). Centres of the buserite aggregates are formed by birnessite with average...schwertmannite, ferrihydrite-2L, buserite-Ca, birnessite, history of slate mining, roofing slate industry, Early...characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ. Geochim Cosmochim Acta 73: 889-910 Bilinsky
Journal (article/letter/editorial)
in the hyporheic zone of rivers contaminated by mining operations (Fuller and Harvey, 2000). Laboratory...line 10.3.2 at the Advanced Light Source (Berkeley, USA; Marcus et al., 2004b). Because Zn can be tetrahedral...characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ. Geochim. Cosmochim. Acta 73, 889–910. Bodeı̈...in the hyporheic zone of a mining-contaminated stream, Pinal Creek, Arizona. Environ. Sci. Technol. 34...mechanism of formation from Na-rich monoclinic buserite at low pH. Am. Mineral. 85, 826–838. Lanson B
Journal (article/letter/editorial)
(Frierdich et al., 2011), the streambed of Pinal Creek, Arizona, U.S.A. (Lind and Hem, 1993), tailings-pond...oxidized to Mn(IV) oxide (buserite) besides Mn(III) oxide (manganite) (Fig. 7a). Buserite has the same Mn layer... J. B. (1987) Transformation of birnessite to buserite, todorokite, and manganite under mild hydrothermal...particulates in the streambed of Pinal Creek, Arizona, USA: a mining-related acid drainage problem. Appl...mechanism of Co2+ oxidation by the phyllomanganate buserite. Am. Mineral. 82(11-12), 1150-1175. Marafatto
Journal (article/letter/editorial)
metal sorption has received little attention in mining-impacted environments, where heavy metal concentrations...layers, in soil profiles from a former uranium mining site in Ronneburg, Germany. Detailed soil profiling...Heavy metals discharged from industrial processes, mining activities and municipal wastes are widespread... such as near-surface environments impacted by mining activities, is the deposition of Mn and Fe (hydr)oxides...environments is important however, because the majority of mining impacted environments are characterised by acidic
Journal (article/letter/editorial)
column; and (iii) the ability of birnessite and buserite/todorokite to strongly scavenge Co, Ni, and Cu...7 Å (birnessite) and 10 Å (todorokite and/or “buserite”) manganates. Vernadite (δ-MnO2) might be present...reflections of the birnessite and/or todorokite/”buserite”. This explains why the vernadite is difficult...between todorokite ACCEPTED MANUSCRIPT and “buserite” is not possible with X-ray analyses alone since...Burns, 1977). The 10 Å interlayer spacing of “buserite” is known to collapse to the typical 7 Å birnessite
Journal (article/letter/editorial)
63130, USA Center for Materials Innovation, Washington University, Saint Louis, MO 63130, USA a r t..., 1985). Caves in Colorado, South Dakota, and Arizona are reported to contain Fe oxides with As and Pb...oxide minerals in the Pautler Cave System, Illinois, USA, were investigated in order to explore the role of...of the karst features here are located in Monroe County, IL, and the area is known to contain the longest...used for all wet chemistry work. Air-stable Ca-buserite was synthesized according to an already published
Journal (article/letter/editorial)
early diagenetic nodules todorokite coexists with buserite (Arrhenius and Tsai 1981; Ito et al. 1998), a...has a 10 Å d-spacing (Giovanoli et al. 1975). Buserite is a two-water (2W) layer hydrated form of the...Drits et al. 1997; Lanson et al. 2000). Synthetic buserite loses one water-layer (1W) and collapses to 7...Na+. When exchanged with Mg2+ or Ca2+, synthetic buserite collapses only at 110 °C or in vacuum, a result...vernadite are used henceforth for randomly stacked buserite and randomly stacked birnessite, respectively
Journal (article/letter/editorial)
retain two planes of interlayer H2O molecules (i.e. buserite) or when an additional octahedral brucite-like...38-0475), may be prepared by heating Mg-exchanged buserite either in an autoclave or at atmospheric pressure...et al., 1964; Taylor, 1968). Similarly, in mining district sediments Co concentration is also positively...be difficult to distinguish tectomanganate from buserite, lithiophorite- or asbolane-like phases using...and 4.8 Å (002) (see buserite JCPDS 32-1128). Both birnessite and buserite also have hk reflections/bands
Journal (article/letter/editorial)
characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ. Geochim. Cosmochim. Acta, 73, 889–910. Barrett...oxides forming in the hyporheic zone of Pinal Creek, Arizona. Environ. Sci. Technol., 48, 2165–2172....mechanism of formation from Na-rich monoclinic buserite at low pH. Am. Mineral., 85, 826–838. Lanson,...mechanism of Co2þ oxidation by the phyllomanganate buserite. Am. Mineral., 82, 1150–1175. Manceau, A., Marcus...Experimental Physics Control Systems, San Francisco, USA, 7–11 October 2013”. Peacock, C.L. & Sherman, D.M
Journal (article/letter/editorial)
presence of 10 Å d-spacings, suggesting todorokite or buserite (Bilinski et al., 2002; Tan et al., 2010). These...confused with layered-structure minerals like buserite and demonstrated that these Mn oxides cannot be...todorokite, and discussed the transformation of buserite to todorokite under different conditions. Webb...characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ. Geochimica et Cosmochimica Acta 73, 889–910...oxides in cemented streambed crusts from Pinal Creek, Arizona, USA, and in hot-spring deposits from Yuno-Taki
Journal (article/letter/editorial)
experimentally by the formation of todorokite from buserite, a 3D-ordered analog to 10Å-vernadite (Giovanoli...oceanic sediments for prospective exploration and mining activities. In metalliferous ferromanganese oxides...could be designated also as defective hexagonal buserite or 10Å-birnessite (see Manceau et al., 2007a...semi-periodic stack of layers (i.e., defective buserite crystals). The positions of the three regions...al., 2002b) followed by its transformation to buserite (i.e., 10Å-birnessite) by exchanging Na with
 
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