| Alpeite | Ca4Mn23+Al2(Mn3+Mg)(SiO4)2(Si3O10)(V5+O4)(OH)6 |
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| Aradite | BaCa6[(SiO4)(VO4)](VO4)2F |
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| Bakakinite | Ca2V2O7 |
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| Barnesite | (Na,Ca)V6O16 · 3H2O |
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| Beckettite | Ca2V6Al6O20 |
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| Burnettite | CaVAlSiO6 |
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| Burroite | Ca2(NH4)2(V10O28) · 15H2O |
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| Calciodelrioite | Ca(VO3)2 · 4H2O |
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| Carbokentbrooksite | (Na3Na3Na3Na3Na3)Ca6(VMn32+)Zr3[Si3O9]2[Si9O27SiO][Si9O27Nb(OH)3](CO3)(H2O) |
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| Caseyite | [(V5+O2)Al10-x(OH)20-2x(H2O)18-2x]2[H2V4+V95+O28][V105+O28]2(Na,K,Ca)2-y(SO4)2-z · (60+8x+y+4z)H2O (x = 0-2.5; y = 0-2; z = 0-2) |
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| Cassagnaite | (Ca,Mn2+)4(Fe3+,Mn3+,Al)4(V3+,Mg,Al)2(Si3O10)(SiO4)2(OH,O)8 |
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| Cavansite | Ca(VO)Si4O10 · 4H2O |
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| Cavoite | CaV34+O7 |
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| Cortesognoite | CaV2(Si2O7)(OH)2 · H2O |
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| Corvusite | (Na,K,Ca,Mg)2(V5+,V4+,Fe2+)8O20 · 6-10H2O |
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| Delrioite | CaSr(V2O6)(OH)2 · 3H2O |
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| Donowensite | Ca(H2O)3Fe23+(V2O7)2 |
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| Fernandinite | (Ca,K)(V5+,V4+,Fe2+)8O20 · 10H2O |
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| Fulbrightite | Ca(VO)2(AsO4)2 · 4H2O |
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| Gatewayite | Ca6(As3+V34+ V95+As65+O51) · 31H2O |
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| Goldmanite | Ca3V23+(SiO4)3 |
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| Gottlobite | CaMg(VO4)(OH) |
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| Grantsite | (Na,Ca)2+x(V5+,V4+)6O16 · 4H2O |
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| Gunterite | Na4Ca(V10O28) · 20H2O |
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| Hanjiangite | Ba2CaV3+Al(H2AlSi3O12)(CO3)2F |
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| Hendersonite | (Ca,Sr)1.3V6O16 · 6H2O |
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| Hewettite | CaV6O16 · 9H2O |
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| Hydropascoite | Ca3(V10O28) · 24H2O |
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| Kannanite | Ca4Al4(AlMg)(VO4)(SiO4)2(Si3O10)(OH)6 |
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| Kegginite | Pb3Ca3[AsV12O40(VO)] · 20H2O |
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| Kokinosite | Na2Ca2(V10O28) · 24H2O |
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| Koksharovite | CaMg2Fe43+(VO4)6 |
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| Lumsdenite | NaCa3Mg2(As3+V24+V105+As65+O51) · 45H2O |
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| Magnesiopascoite | Ca2Mg(V10O28) · 16H2O |
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| Melanovanadite | Ca(V5+,V4+)4O10 · 5H2O |
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| Mesaite | CaMn52+(V2O7)3 · 12H2O |
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| Metadelrioite | CaSr(V2O6)(OH)2 |
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| Metahewettite | CaV6O16 · 3H2O |
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| Metarossite | Ca(V2O6) · 2H2O |
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| Metatyuyamunite | Ca(UO2)2(VO4)2 · 3H2O |
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| Midbarite | Ca3Mg2(V2Si)O12 |
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| Morrisonite | Ca11(As3+V24+V105+As65+O51)2 · 78H2O |
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| Mukhinite | (CaCa)(AlAlV3+)O[Si2O7][SiO4](OH) |
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| Nashite | Na3Ca2[(V95+V4+)O28] · 24H2O |
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| Packratite | Ca11(As3+V105+V24+As65+O51)2 · 83H2O |
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| Palenzonaite | (NaCa2)Mn22+(VO4)3 |
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| Pandoraite-Ca | CaV54+V25+O16 · 3H2O |
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| Pascoite | Ca2Ca(V10O28) · 17H2O |
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| Pentagonite | Ca(VO)Si4O10 · 4H2O |
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| Phosphovanadylite-Ca | Ca[V44+P2O12(OH)4] · 12H2O |
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