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General"Hourglass" inclusions

15th Apr 2024 19:22 UTCTed Hadley

A recent post about Moroccan amethyst piqued my interest here. I can immediately think of three minerals which have "hourglass" shaped inclusions or internal patterns: brookite (especially when tabular), gypsum, and Moroccan amethyst.

Why?
What causes this to happen?
Does it occur in other minerals?
When in other minerals, does it have the same cause?

Furthermore, gypsum can have two types of inclusions, "sand" (common in Oklahoma selenite) and LW fluorescent (but otherwise colorless and invisible) inclusions most common in Alberta selenite, but fairly commonly present in other samples too. The fluorescent pattern matches the crystallographic planes as do the sand inclusions, so the are all related.

What is going on here?


Thanks

Ted

15th Apr 2024 20:08 UTCEd Clopton 🌟 Expert

A crystallographer can (and maybe will) give a more rigorous explanation, but here's my layman's understanding of it:

Different faces of various crystal forms have different properties when it comes to attaching new molecules to the crystal.  Some faces present more favorable sites for attachment of new molecules, so growth is faster (and the crystal becomes longer) in those directions.  Certain faces--maybe the same ones, maybe different ones--"catch" impurities more easily, whether it is sand in Oklahoma gypsum crystals, fluorescent or fluorescence-activating impurities in Alberta gypsum, or purple coloring agents in Moroccan amethyst.

Why the hourglass shape?  Early in its existence the crystal is small, and the faces that catch impurities are small.  As the crystal extends in that direction, the faces become progressively wider as the sides fill in (albeit more slowly) as well.  The result is a series of progressively wider zones of inclusions which end up forming an hourglass shape.

Opaque crystals surely form hourglass zones more often than we realize because we can't see their interiors easily.  I suspect the X-shaped zones in the chiastolite variety of andalusite probably form something like hourglass shapes, and that probably applies to the figures in "cherry blossom stone" muscovite pseudomorphs after cordierite as well.

15th Apr 2024 21:21 UTCTed Hadley

So it sounds like you're kinda describing hopper growth which is later overgrown.

16th Apr 2024 10:55 UTCEd Clopton 🌟 Expert

So it sounds like you're kinda describing hopper growth which is later overgrown.
Not exactly.  Hopper growth involves external crystal faces that form in a hopper shape.  That occurs when growth is fastest along the edges of a crystal--the edges extend outward but the faces don't get filled in.

Hourglass inclusions develop as complete layers, containing impurities on certain faces and free of impurities on others, are added as the crystal grows.  The hourglass shape in an included crystal was not a free-standing hopper form that later became enclosed.  Imagine repeatedly painting just the ends of a transparent crystal as it grows.  The unpainted sides would remain clear, but the painted ends eventually would form an hourglass.

15th Apr 2024 21:44 UTCRalph S Bottrill 🌟 Manager

When cracks form in crystals they can slowly heal under hydrothermal conditions, via a process that can cause necking, hourglass shapes and eventually a string of rounded fluid inclusions. During crystal growth you sometimes get linear fluid inclusions that could heal in a similar manner.

15th Apr 2024 22:17 UTCMax Merlo

"Does it occur in other minerals?"


16th Apr 2024 11:12 UTCDalibor Matýsek

It is probably a slightly different case, but sector zonality in the form of an hourglass can quite often be observed microscopically in petrographic cross-sections of titanium-rich diopside crystals. It is claimed to be a kinetic phenomenon associated with crystallization. individual sectors tend to have a slightly different composition.

16th Apr 2024 11:52 UTCDalibor Matýsek

For that amethyst there is this literature:

17th Apr 2024 17:39 UTCLalith Aditya Senthil Kumar

Found siderite in the search section, but cannot see an hourglass formation. 
Would this hourglass be considered praseolite?

20th Apr 2024 22:04 UTCMax Merlo

Well, in the first reference you give the inclusion is not referred to Aeschynite but to the brookite, in the Calcite is referred to an optical effect and in the last ones, Ankerite-Dolomite, Gratonite, Pezzotaite, Smithsonite the term is referred to the external shape and not to an "hourglass" shaped inclusions, therefore would not add these minerals to the previous list.
 
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