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Crystallography: The Monoclinic System

Last Updated: 26th Apr 2024

By Donald Peck & Alfred Ostrander

According to the International Union for Crystallography

09866760015031498146795.jpg
Gypsum (Prismatic Class)
08116320014947337642109.jpg
Diopside (Prismatic Class)
08789580014961354113119.jpg
Uranophane (Sphenoidal Class)
01089500014949394334193.jpg
Clinohedrite (Domatic Class)
05993910014950746322143.jpg
Gypsum (Prismatic Class)
00533530014977421572912.jpg
Diopside (Prismatic Class)
03304010014998117552098.jpg
Uranophane (Sphenoidal Class)
08838130015308341743117.jpg
Clinohedrite (Domatic Class)
09643140014950342388782.jpg
Gypsum (Prismatic Class)
08116320014947337642109.jpg
Diopside (Prismatic Class)
08789580014961354113119.jpg
Uranophane (Sphenoidal Class)
01089500014949394334193.jpg
Clinohedrite (Domatic Class)


The monoclinic crystal system embraces nearly 1,400 different mineral species (2018), or approximately 27% of all known minerals. That population is, by far, the largest of the seven crystal systems. The system is comprised of three crystal classes: the prismatic class, the sphenoidal class, and the domatic class. With more than 1,200 mineral species in the prismatic class alone it is worthwhile to become thoroughly acquainted with the symmetry of the class. The remaining two classes each hold slightly more than 80 different minerals.

You may find it helpful to review the following articles before attempting this one:
Determining Symmetry of Crystals: An Introduction
Miller Indices
Hermann-Mauguin Symmetry Symbols

Unique Symmetry of the Monoclinic System


The monoclinic crystal system is characterized by a 2-fold axis of rotational symmetry coincident with the b-axis; or a mirror plane that includes the c-axis and the a-axis; or both. Usually, it is both. The prismatic class shows the 2-fold axis perpendicular to the mirror plane and it has a center of symmetry. The sphenoidal class has only the 2-fold axis (no mirror plane and no center of symmetry). And the domatic class has the mirror plane, but no 2-fold axis and no center of symmetry. The monoclinic crystal system is one of low symmetry. The only system with lower symmetry is the triclinic system.

The 2-fold axis of rotational symmetry as the principal axis of symmetry, coincident with the b-axis, is unique to the monoclinic crystal system. All others have the c-axis as the principal axis of rotational symmetry (or the vertical a-axis in the isometric system).


Crystallographic Axes

00519000015238206708989.jpg
Axes: Monoclinic Crystal System

The symmetry of the monoclinic system generates a three axis model (The axes are a result of the symmetry, not vice-versa). The axes are designated a, b, and c. The b and c axes are in the same plane and intersect at a 90o angle. The a axis is usually inclined to the c axis and makes an angle of 90o to the b axis. By custom, the positive end of the a axis (a+) pitches downward relative to the c axis. The angle between the a and c axes is designated as β (beta) and is usually greater than 90o. (Beta is the angle of rotation of the a+ axis from the c+ axis around the b axis.) In some references, the a axis is often referred to as the clino axis and the b axis as the ortho axis.

Symmetry determines the direction of the b axis, which is the standard unit. A prominant sloping face is usually considered to be parallel to the a axisl And if the crystal is elongated in the plane of the a and c axes, the longer of the two axes is usually chosen as c.

There are approximately 80 monoclinic minerals where β equals 90o. You may well ask how this can be. Recall that the symmetry determines the axes, so if the symmetry is monoclinic, the a axis may be perpendicular to the c axis. Two with which you may be familiar are mesolite, in the sphenoidal class, and neptunite, in the domatic class. In both cases β is 90o but α is unequal to 90o.

Angular observations must be made carefully, as there are another 100, or so, species where β is between 91o and 93o.

General and Special Forms


There are two types of forms, general forms and special forms.

Any form which is not a general form is a special form. Most often, the general form is the form for which the crystal class is named. A general form has the maximum number of faces of any form in its crystal class. Special forms are not unique to a particular class but may appear in several classes.


The general form intercepts all three axes, each at a different axial unit distance. Thus the Miller index for each axis will have a different value. It might be {123}, {431}, {314}, or something similar. It is the form for which the mineral class is named and which generates the maximum number of faces relative to other forms in the crystal class. It is not always expressed on the crystal.

Special forms have Miller Indices like {100}, {110}, {111),{102}, etc. Special forms may be found on crystals in any crystal class of the system.

Forms Found on Monoclinic Crystals

Monoclinic Forms

Prisms & Domes
00954950015247035108484.jpg
{hkl}; 4th Order Prism Positive
06942720015247038641637.jpg
{0kl}; 1st Order Prism
01432200015247037576178.jpg
{hk0}; 3rd Order Prism
06208670015323627804676.jpg
3rd Order Dome
Pinacoids
07568990015247063285451.jpg
{h0l]; 2nd Order Pinacoid Positive
01186490015247055462276.jpg
{100}; a Pinacoid
04829340015247059999808.jpg
{010}; b Pinacoid
08396300015247061509420.jpg
{001}; c Pinacoid; Basal Pinacoid
00743880015247072652938.jpg
Generalized Monoclinic Crystal

The Generalized Monoclinic figure,at the right indicates the relative position of the faces for each form on the crystal.

Prism
A prism is an open form with three or more similar faces surrounding an axis (the ends are not closed by a face of the same form).
In the monoclinic system, a prism is comprised of four faces. The {hkl} prism is a 4th order prism. There is a positive 4th order prism in which the two faces on the upper half of the crystal intercept the positive end of the a-axis. And there is a negative 4th order prism in which the two faces on the upper half of the crystal intercept the negative end of the a-axis. They are not interchangeable. The {hkl} prism shown above is 4th order positive. The positive and negative forms, taken together, comprise a dipyramid that has eight faces. Together they make a closed form. That is, extended, they completely enclose space. Either the positive form or the negative form, or both, may be present on a monoclinic crystal.

The {0kl} prism is the 1st order prism (it surrounds the a-axis); the {hk0} prism is 3rd order (it surrounds the c-axis). There is no 2nd order prism because the system's symmetry (and inclination of the a-axis) does not permit four similar and parallel faces to surround the b axis.

A Dome is "half a prism". It consists of two intersecting faces, parallel to an axis, and separated by a mirror plane. Domes parallel to the c-axis are possible.

Pinacoids
A pinacoid is a pair of parallel faces. It is an open form, not closed on the sides or ends by faces of the same form.

The {100} pinacoid is parallel to the the plane of the b and c axes and constitutes the "front" and "back" of the crystal. Similarly {010} is the "sides" and {001) the "top" and "bottom". It is important to note that the plane of {001) is parallel to the plane of the a and b axes, and not perpendicular to the c axis.

The {hol} intercepts the a and c axes and is parallel to the b axis. The form is positive if the intercept of the face on the upper half of the crystal is on the positive end of the a axis. The form is negative if the intercept of the face on the upper half of the crystal is on the negative end of the a axis. Some texts refer to these forms as clinodomes. Together they may resemble a 2nd order prism, but they are not.

General Morphology


Monoclinic crystals are generally prismatic or acicular. Occasionally they will be tabular. Cross-sections range from nearly square to rectangular or rhombic; and may appear nearly octagonal or hexagonal.

In a view of the termination, down the c axis, there is almost always a mirror plane that includes the a-axis and c-axis. Generally, the faces of the upper termination above the a+ axis are distinctly different than those above the a- axis. The absence of a second mirror plane, perpendicular to the first usually, but not always, will differentiate monoclinic symmetry from orthorhombic symmetry (The orthorhombic disphenoidal class does not have mirror planes that include the c-axis).

The angle, β, often is readily visible. A view along the b-axis usually shows β as asymmetry in the termination. The inclined face, (001), is parallel to the plane of the a-axis and b-axis. {It is not perpendicular to the c-axis.} β, then, is the larger of the angles that the plane (001) makes with the c-axis (usually parallel to the vertical edge of the crystal). A measured angle less than 90o must be subtracted from 180o in order to obtain beta.

Although there are three crystal classes in the monoclinic crystal system, only the prismatic class is commonly encountered. Mineral that crystallize in the sphenoidal and domatic classes are relatively rare and few in number. The sphenoidal class is important in other scientific fields, particularly chemistry, for its optical properties.

The Crystal Classes


The monoclinic crystal classes, listed below, are in order of decreasing population, not in decreasing symmetry as they are sometimes listed in other references. The prismatic class holds, by far, the largest number of species of any class in any of the seven crystal systems. The sphenoidal and domatic classes have lower symmetry and hold comparatively few mineral species.

The Prismatic Class

Herman-Mauguin Symbol
2/m (read as a 2-fold axis of rotation perpendicular to a mirror plane. An axis of rotational symmetry perpendicular to a mirror plane always produces a center of symmetry).

Symmetry Elements
1A2,1P, C (One 2-fold axis of rotational symmetry, 1 plane of symmetry, a center of symmetry).
Holohedral (The highest symmetry class of its system)

General Form
The general form, if present, is always a monoclinic 4th order prism{ hkl} where hklh and h≠0≠k≠0≠l. In the Prismatic Crystal Class it is expressed as two faces modifying the corners above the >a+ axis and two faces below the a- axis.

Special Forms
Any of the following forms may be present:
Pinacoids: {100}, {010}, {001}, {h0l}+, {h0l}-
Prisma: {0kl}, {hk0}, {hkl}+, {hkl}-

Look For
A vertical mirror plane that includes the a and c axes. The absence of a vertical mirror plane that includes the b and c axes. A (001) face inclined to the c axis.

Problems

1. Most often, we deal with crystals that are on matrix. In such cases, the lower termination is not available and the 2-fold axis can be inferred, but not observed. The inclined a axis, with the inclined (001) face, is likely the first observation to indicate a monoclinic crystal. With the single mirror plane visible from the front, back, and especially the upper termination and the absence of a second mirror plane perpendicular to the first, the prismatic class becomes almost certain.
2. When the beta angle is 90o, or very close to it, the (100) face does not appear to be inclined when viewed along the b axis. Then one must rely on the observation of the single mirror plane, which is probable for the monoclinic prismatic class, but is not certain.

Toggle
Edge Lines | Miller Indices | Axes

Transparency
Opaque | Translucent | Transparent

View
Along a-axis | Along b-axis | Along c-axis

{100}, {010}, {001}, {22-1}, modified
Locality: Achmatowsk, Ural
Kokscharow, 1862. In: V.M. Goldschmidt, Atlas der Krystallformen, 1913-1923 ('Monokline Pyroxene (Diopsid)').

The crystal depicted above is of diopside, a typical mineral in the monoclinic prismatic class. Turn on the axes.
Symmetry
1 Axis of 2-fold Rotational Symmetry: Coincident with the b-axis
1 Mirror Plane, vertical, the plane of the a and c-axes.
Forms:
Prisms:
2 1st Order, (110} & {313}
1 4th Order, 211, Negative, (Upper half intercepts negative end of a-axis)
Pinacoids: 3, a {100}, b {010}, c {001}
1 2nd Order Pinacoid, 101, Negative, (Upper half intercepts negative end of a-axis)

Representative Minerals: Actinolite, Azurite, Clinoclase, Hydromagnesite, Monazite-(Ce), Orthoclase, Realgar,Staurolite

The Sphenoidal Class

Herman-Mauguin Symbol
2 Only a 2-fold axis of symmetry. There is no mirror plane and no center of symmetry.

Symmetry Elements1 A2 (which is 1 2-fold axis of rotational symmetry {the b axis}). Prisms become sphenoids
Crystals in this class are enantiomorphic (showing left or right handedness; crystals are very similar, but one cannot be superimposed on the other.)

Forms
{100} and {h0l} pinacoids may be present.
Pinacoids perpendicular to the b axis become pedions (A single faced form resembling half a pinacoid). The 1st, 3rd, and 4th order prisms alter to sphenoids which are enantiomorphic. A sphenoid is an open form that has two faces related to each other by a 2-fold axis and that are not parallel to each other (think of clipping two diagonal corners off the top of a shoebox).

Problems
The minerals in this class tend to be fibrous, radiating, and acicular. About the best that one can hope for is to find radiating crystals large enough so the inclined {001} face is observable as a termination of the crystal. Recognizing the class is difficult.

Representative Minerals: Halotrichite, Pickeringite, Uranophane, Wollastonite-2M

The Domatic Class

00802680016010752965536.jpg
Clinohedrite
Herman-Mauguin Symbol
m = 2

Forms
This class has extremely low symmetry. Pinacoids that are on opposite sides of the mirror plane become pedions (i.e. The two faces are no longer mirror images of each other). Domes (two intersecting (possibly by extension) faces that lie on opposite sides of the mirror plane. Domes are an open form.

Symmetry Elements
P (1 mirror plane.) The Holohedral class (The lowest symmetry of any class in its system.) Also, minerals in this class are hemimorphic (the forms at one end of the principal axis are different from those at the other end). Prisms become domes. that is, two adjacent faces of the prism remain forming a dome, while the other two faces are not expressed.

Look For
Look for the inclined {001} face and the single mirror plane in the plane of the a and c axes.
If both ends of the c axis are visible, look for the hemimorphism. In the stereophoto at the right, the(001) face is uppermost with the mirror plane running left to right.

Problems
If the crystal is on matrix, differentiating this class from the prismatic class is virtually impossible. The minerals in this class are not common.

Clinohedrite

Toggle
Edge Lines | Miller Indices | Axes

Transparency
Opaque | Translucent | Transparent

View
Along a-axis | Along b-axis | Along c-axis


Penfield & Foote (1898), and others. In: V.M. Goldschmidt, Atlas der Krystallformen, 1913-1923 ('Klinoedrit').
.
Symmetry
1 Mirror Plane: the plane of the a and c axis.
Forms
Prism: 3rd Order {110}; 3rd Order {120}; 4th Order {131}
Domes: 3rd Order (320); 4th Order-Negative (551}; 4th Order-Negative {-531}
Pinacoid: {010}

Representative Minerals: Clinohedrite, Neptunite, Scolecite


Links to the Crystallography of each of the systems.


Crystallography: The Monoclinic System
Crystallography: The Orthohombic System
Crystallography: The Trigonal System
Crystallography: The Hexagonal System
Crystallography: The Tetragonal System
Crystallography: The Isometric System

References


Mason, Brian and Berry, L.G. (1968) Elements of Mineralogy. W. H. Freeman and Company, San Francisco.
Dana,Edward Salisbury; Foord, William E. (editor); A Textbook of Mineralogy. John Wiley & Sons, Inc., New York
Sinkankas, John: Mineralogy: A First Course. A great book with which to start.
Peck, Donald B. (2007) Mineral Identification: A Practical Guide for the Amateur Mineralogist. Mineralogical Record, Tucson, Arizona.
A.E.H Tutton,Crystallography and Practical Crystal Measurement Volume 1 Form and Structure; 2018. An incredibly thorough text. Not for the beginner.
Klein, Cornelis & Hurlbut, Cornelius S., Jr.: Manual of Mineralogy after J. D. Dana;20th Edition
http://www.minsocam.org/ammin/AM20/AM20_838.pdf: Rogers, Austin F. (1935) A historical discussion of the names of crystal forms.
https://en.wikipedia.org/wiki/Monoclinic_crystal_system , Short explanation of lattices, space groups, hemimorphic & enantiomorphic structure.

Acknowledgements


Our thanks to Erin Delventhal, who helped with the formatting.

Photo Credits: Gypsum: Chinellato Matteo; Diopside: Scott M. Whittemore; Uranophane: SMS; Clinohedrite: Marko Burkhardt.






Article has been viewed at least 33638 times.

Discuss this Article

Crystallography: The Monoclinic System

5th May 2018 18:10 UTCDonald B Peck Expert

According to the International Union for Crystallography

Gypsum (Prismatic Class)Diopside (Prismatic Class)Uranophane (Sphenoidal Class)Clinohedrite (Domatic Class)

The monoclinic crystal system embraces nearly 1,400 different mineral species (2018), or approximately 27% of all known minerals. That population is, by far, the largest of the seven crystal systems. The system is comprised of three crystal classes: the prismatic class, the sphenoidal class, and the domatic class. With more ...

Click here to view the full article

11th Feb 2024 15:36 UTCDiego Benites

Thank you very much for such good information about the monoclinic system. 

Most mineralogy texts do not indicate that beta can be equal to 90 degrees. In fact, they always emphasize that beta is the only one that can be different (greater) than 90 degrees. So, if I understood, some monoclinic minerals that have beta = 90 degrees, it is because either alpha or gamma (one of the two is different from 90), right? 

Thanks


20th Apr 2024 22:47 UTCRalph S Bottrill 🌟 Manager

These pages are generally pretty good but there are a few typos, errors, bad links etc, is it ok if we fix them?

Edit: I fixed a couple typos and bad links. I did not check all links as the system seems very slow currently.

12th Feb 2024 15:10 UTCRob Woodside 🌟 Manager

Thank you very much for this wonderful article. Over twenty years ago when I joined Mindat, this was the kind of article I hoped I might eventually see. Thanks so much for your excellent work on all the xl systems. These really are a must read if anyone wants to learn how to spot symmetries in real xls.

20th Apr 2024 02:04 UTCLeon Rozenshteyn

wow. just wow

21st Apr 2024 00:07 UTCA. A. Faller

As above! This article has convinced me to really hunker down
and actually derive some benefits from obtaining this knowledge,
that I will especially apply when viewing microcrystals/micromounts.
Now, I look forward to the subsequent articles in the series as well.
Thanks, indeed...
 
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