 | Kars, Myriam, Lerouge, Catherine, Grangeon, Sylvain, Aubourg, Charles, Tournassat, Christophe, Madé, Benoît, Claret, Francis (2015) Identification of nanocrystalline goethite in reduced clay formations: Application to the Callovian-Oxfordian formation of Bure (France) American Mineralogist, 100 (7) 1544-1553 doi:10.2138/am-2015-5096 | Journal (article/letter/editorial) | | nanocrystalline goethite in reduced clay formations: Application to the Callovian-Oxfordian formation of Bure (France)...measurements performed show that magnetite and goethite are the main magnetic minerals (<0.2%), together...probable greigite, and occur in low concentrations. Goethite occurs as nanoparticles dispersed in the clayey...or in organic matter. It is unlikely that the goethite is an alteration by-product, as particular care...observations and previous modeling results. Keywords: Goethite, nanoparticles, Callovian-Oxfordian clay formation |  | Aubourg, Charles, Kars, Myriam, Pozzi, Jean-Pierre, Mazurek, Martin, Grauby, Olivier (2021) A Magnetic Geothermometer in Moderately Buried Shales. Minerals, 11 (9) 957 doi:10.3390/min11090957 | Journal (article/letter/editorial) | | 3390/min11090957 Keywords: shales; magnetite; goethite; oil window; geothermometer Academic Editor:...parameter versus peak burial temperature natural shales Bure) and laboratory-heated The oil temperature of natural...natural shalesof(Opalinus and (Opalinus Bure) andand laboratory-heated shales. The shales. oil window...Opalinus Clay (Dogger) from the Jura mountains and Bure Clay (Callovo-Oxfordian) from the Paris Basin. The...The peak burial temperature of Opalinus and Bure shales has been estimated at ~85 ◦ C and ~40 ◦ C, respectively |  | Gailhanou, H., Lerouge, C., Debure, M., Gaboreau, S., Gaucher, E.C., Grangeon, S., Grenèche, J.-M., Kars, M., Madé, B., Marty, N.C.M., Warmont, F., Tournassat, C. (2017) Effects of a thermal perturbation on mineralogy and pore water composition in a clay-rock: An experimental and modeling study. Geochimica et Cosmochimica Acta, 197. 193-214 doi:10.1016/j.gca.2016.10.004 | Journal (article/letter/editorial) | | observing the neoformation of minerals such as goethite we were able to assess the prominent role of Fe-bearing...at 25 °C in the Callovian-Oxfordian clay-rock at Bure (France) from Gaucher et al. (2009) is summarized...Si, Al, Fe in the CallovianOxfordian clay-rock (Bure, France) at 25 °C. Bottom: corresponding predicted...the Andra underground research laboratory (URL) at Bure (France) (Claret et al., 2010; Kars et al., 2015)...warmed to 400 K, above the Néel temperature of goethite (393 K; Özdemir and Dunlop, 1996) and cooled |  | | Journal (article/letter/editorial) | | maturation: immature (burial temperature ∼ 40 °C) of Bure Callovo–Oxfordian claystones in the Basin of Paris...magnetization (CRM) at 95 °C for several weeks in Bure and Opalinus claystones. Thermal demagnetization...assemblage of magnetite and iron sulphide is formed in Bure claystones. Further, we document the appearance...appearance of a magnetic transition at ∼ 35 K in Bure claystones after heating. We name this transition the P-transition...currently investigated for nuclear waste storage (Bure and Opalinus claystones) and one site in the Chartreuse |  | | Report (chapter) | | laboratory heating at 95 8 C Two Bure and Opalinus claystones are studied. The Bure claystones (Callovo–Oxfordian)...temperature near 85 8C (Mazurek et al. 2006). The NRM of Bure and Opalinus claystones are low (,0.5 mA m2 kg21)...Fig. 1. Laboratory heating experiments at 95 8C. Bure claystones (EST-211– 675 m): four samples. Opalinus... (2008). Opalinus claystones (five samples) and Bure claystones (four samples) show the development of...claystones and 35 + 6 mA m2 kg21 at 27 days for Bure claystones. The TVRM represents about half of the |  | Gaucher, E.C., Tournassat, C., Pearson, F.J., Blanc, P., Crouzet, C., Lerouge, C., Altmann, S. (2009) A robust model for pore-water chemistry of clayrock. Geochimica et Cosmochimica Acta, 73 (21) 6470-6487 doi:10.1016/j.gca.2009.07.021 | Journal (article/letter/editorial) | | France (Callovo-Oxfordian (COx) clayrock at Bure), Belgium (Boom Clay at Mol), Hungary (Boda clayrock...of these formations (Belgium at Mol, Switzerland at Mont Terri, France at Bure). Here we will use data...data obtained in experiments carried out in the Bure A robust model for pore-water chemistry of clayrock...situated in the Callovo-Oxfordian (COx) clays at Bure (France) are then discussed. The remainder of this...composition of pore water present in the COx at the Bure URL. This programme was carried out in two phases |  | | Report (chapter) | | as a host rock for a repository (Switzerland, Belgium, France; Nagra 2002; ONDRAF 2004; ANDRA 2005),...discussed, for example, for the clayey formation of Bure by Lerouge et al. (2011). Biofilm formation Microbes...adopted in different countries (carbon steel in Belgium, France and Switzerland or copper in Sweden, Finland...disposal architecture pursued at that time in Belgium. In this experiment, a heat-generating stainless...(hydr)oxides. Indeed, comparable rates of, for example, goethite dissolution have been observed in the presence |  | Lerouge, Catherine, Grangeon, Sylvain, Claret, Francis, Gaucher, Eric, Blanc, Philippe, Guerrot, Catherine, Flehoc, Christine, Wille, Guillaume, Mazurek, Martin (2014) Mineralogical and Isotopic Record of Diagenesis from the Opalinus Clay Formation at Benken, Switzerland: Implications for the Modeling of Pore-Water Chemistry in a Clay Formation. Clays and Clay Minerals, 62 (4) 286-312 doi:10.1346/ccmn.2014.0620404 | Journal (article/letter/editorial) | | same diagenetic sequence (Rupelian Boom Clay, Belgium: Laenen and De Craen, 2004; Tournemire Toarcian...Toarcian Clay, France: Peyaud et al., 2006; Bure Callovo-Oxfordian (COx) Clay, France: Lerouge et al., 2011;...are also present in the Rupelian Boom Clay Fm in Belgium (Laenen and De Craen, 2004) and in the Oxfordian...the formation whereas the COx Clay Formation at Bure, France, contains little siderite disseminated in...exchanger, Ca by calcite saturation, Fe by siderite or goethite saturation, Mg by the cation exchanger or the |  | | Book | | (Arthurton et al., 1994). The presence of abundant goethite ooids within pink and olive-green soft 1nudstone...for example the pre-Holocene valley of the River Bure lies at least 7..5 m below OD under the marshland...hinterland. By this ti1ne, it is likely that the Rivers Bure, Thurne and Ant and Hundred Strea1n of today were...Stream originally drained westwards into the River Bure while the palaeocoastline lay some kilo1netres east...River Thurne/Hundred Strearn back into the River Bure is tmknown. The most likely explanation is that |  | | Report (issue) | | traitement de minerais Pb-Zn-Cu: des oxydes (zincite, goethite, lépidocrocite), des carbonates (aragonite, hydromagnésite...884 t de minerai. - Champ S (c'est-à-dire au S du bure 16, et au-dessus de - 50 m) Surface horizontale...janvier 1863, par la S.A. Vieille-Montagne, par un bure foncé sur le prolongement méridional des minéralisations...hérnirnorphite en proportions équivalentes, limonite, goethite (Mélon et al., 1976), wad (Mélon et al., 1976)...allophane, delvauxite, dolomite (Dumont, 1831), goethite, gypse (Dumont, 1831), halloysite, halotrichite |  | Rivard, C., Pelletier, M., Michau, N., Razafitianamaharavo, A., Bihannic, I., Abdelmoula, M., Ghanbaja, J., Villieras, F. (2013) Berthierine-like mineral formation and stability during the interaction of kaolinite with metallic iron at 90 C under anoxic and oxic conditions. American Mineralogist, 98 (1) 163-180 doi:10.2138/am.2013.4073 | Journal (article/letter/editorial) | | selected the Callovo-Oxfordian (COx) clay stone from Bure, France, as a potential host-rock. This rock contains...percentage). are found together with oxyhydroxides (goethite, FeOOH), which confirms oxidizing conditions....areas as for instance, from 18 to 150 m2/g for goethite (Prélot et al. 2003; Montes-Hernandez et al. 2004;...results. At the same time, peaks corresponding to goethite and hematite appear and their intensities increase...dissolution of lepidocrocite, ferrihydrite, and goethite. Geochimica et Cosmochimica Acta, 65, 1379–2001 |  | Joseph, C., Schmeide, K., Sachs, S., Brendler, V., Geipel, G., Bernhard, G. (2011) Sorption of uranium(VI) onto Opalinus Clay in the absence and presence of humic acid in Opalinus Clay pore water. Chemical Geology, 284 (3) 240-250 doi:10.1016/j.chemgeo.2011.03.001 | Journal (article/letter/editorial) | | dome (Germany, USA), clay (France, Switzerland, Belgium), and granite rock (Sweden, Finland, Canada) with...Hartmann et al., 2008), and Boom Clay from Mol, Belgium (Beauwens et al., 2005; Deniau et al., 2001; Deniau...Switzerland and with Callovo-Oxfordian Clay from Bure, France was investigated by Hartmann et al. (2008)...Mol laboratory (Boom Clay Formation, Oligocene, Belgium): structure, source organisms and formation pathways...thermal reactivity of kerogens from Mol (Boom Clay), Bure (Callovo-Oxfordian argillite) and Tournemire (Toarcian |  | | Book | | Disposal, Mol, Belgium; KU Leuven, Department of Earth & Environmental Sciences, Heverlee, Belgium. E-mail:...Research Centre, Expert Group, Waste & Disposal, Mol, Belgium. E-mail: nmaes@SCKCEN.be Virginie Marry, Sorbonne...tournassat@brgm.fr Agnès Vinsot, Andra, LSMHM, Bure, France. E-mail: agnes.vinsot@andra.fr Acknowledgments...determined that Fe(III)-pillared Mt was as strong as goethite as an adsorbent for As(V) and As(III), thus making...Survey (BRGM), Orle´ans, France; b Andra, LSMHM, Bure, France; c TOTAL, E&P, Pau, France; d Andra, Châtenay-Malabry |  | | Journal (issue) | | de 3 à 8 millimètres et des sphalérites rouges du Bure (Tarn). Signalons au passage que la mine est appelée...ta,rnais d'extraction de "fluorine" : Montroc, Le Bure et Le Moulina] (ou St Jeande-Jeannes), selon Le...petites cavités d'un quartz pyriteux tapissées de goethite. Il s'agit en fait d'un mélange des deux polytypes...d'une belle couleur bleu ciel disposés sur une goethite brun sombre. FRANCIS BEBE Francis Béhé nous a...est très localisée, dans des zones altérées à goethite et limonite de forme lenticulaire et présentant |  | Rivard, Camille, Montargès-Pelletier, Emmanuelle, Vantelon, Delphine, Pelletier, Manuel, Karunakaran, Chithra, Michot, Laurent J., Villieras, Frédéric, Michau, Nicolas (2013) Combination of multi-scale and multi-edge X-ray spectroscopy for investigating the products obtained from the interaction between kaolinite and metallic iron in anoxic conditions at 90 °C. Physics and Chemistry of Minerals, 40 (2) 115-132 doi:10.1007/s00269-012-0552-6 | Journal (article/letter/editorial) | | from the ZIRA (Interest Zone for in-depth study, Bure, France) as a candidate host rock. This rock contains...Maghemite Alfa Aesar Iron oxide c-Fe2O3 x Goethite BASF Iron oxyhydroxide FeO(OH) x Illite ...ferric oxide phases (magnetite, maghemite and goethite) and an iron-rich clay phase (berthierine BStA)...compounds that contain Fe3? only such as maghemite and goethite. Both compounds display rather similar spectra...of the L3 line, indicative of the fact that in goethite, only VIFe is present whereas maghemite contains |  | Ma, Bin, Charlet, Laurent, Fernandez-Martinez, Alejandro, Kang, Mingliang, Madé, Benoît (2019) A review of the retention mechanisms of redox-sensitive radionuclides in multi-barrier systems. Applied Geochemistry, 100. 414-431 doi:10.1016/j.apgeochem.2018.12.001 | Journal (article/letter/editorial) | | repository, named Cigéo, in a clay-rock formation at Bure, in eastern France. The targeted 117 wastes that...such as, magnetite (Fe3O4), hematite (Fe2O3), goethite (FeOOH), 297 and siderite (FeCO3), can also...isotope fractionation analysis, sorbed Fe(II) on goethite via atom exchange amounts 329 to one atomic...onto a series of Fe(III)- 338 oxyhydroxides (goethite, lepidocrocite, nano-sized ferric oxide hydrate...RNs. Besides, FeIII- 346 oxyhydroxides such as goethite can also remove aqueous UVI by surface complexation |  | | Journal (article/letter/editorial) | | corrosion layer containing siderite, magnetite, some goethite, and lepidocrocite mixed with the montmorillonitic...and with a clayrock (Callovo-Oxfordian formation, Bure, France). In both cases, corrosion layers of magnetite...Strong reflections of lepidocrocite, siderite, goethite, and magnetite reveal the presence of both Fe2+...2011). Small reflections indicate the presence of goethite in C5 and of anhydrite in C9. None of the reflections...gypsum, Lepido: lepidocrocite, Sme: smectite, Gth: goethite, Sd: siderite, Anh: anhydrite, Qz: quartz, Mag: |  | | Report (chapter) | | Callovo-Oxfordian claystone (COx) drilled at 2445 m depth at the Bure site (France) was machined, and three probes (12...with the claystone primary minerals (and also goethite, which precipitates during the process) (Table...Nontronite-Na Nontronite-K Nontronite-Mg Magnetite Goethite Pyrrhotite Strontianite Calcedoine SiO2(am.) Lizardite |  | Descostes, M., Blin, V., Bazer-Bachi, F., Meier, P., Grenut, B., Radwan, J., Schlegel, M.L., Buschaert, S., Coelho, D., Tevissen, E. (2008) Diffusion of anionic species in Callovo-Oxfordian argillites and Oxfordian limestones (Meuse/Haute–Marne, France) Applied Geochemistry, 23 (4) 655-677 doi:10.1016/j.apgeochem.2007.11.003 | Journal (article/letter/editorial) | | the Callovo-Oxfordian argillite (illite, pyrite, goethite, organic matter, calcite, dolomite, etc.) would...échantillon d’argilite du Callovo-Oxfordien de Bure (Meuse/Haute marne). Technical report CEA/ DEN/DPC/SECR...Tevissen, E., 2005. Cesium sorption and diffusion in Bure mudrock samples. Appl. Clay Sci. 29, 172–186. Menut...dimensioning of in situ diffusion experiments at Bure. 2nd Internat. Meeting ‘‘Clays in natural and engineered |  | | Journal (article/letter/editorial) | | primarily nano-crystalline domains of Alsubstituted goethite and micron-sized micaceous clay minerals (Coston...well-ordered, nanometer-size domains of Al-substituted goethite; and poorly ordered aluminosilicate nanometer-size...Transformation of poorly ordered Fe(III) oxyhydroxides to goethite, magnetite, and other crystalline Fe(III) oxyhydroxides...transformation of arsenic by Fe(II)-activated goethite (a-FeOOH). Environ. Sci. Technol. 44, 102–108...Hering J. (2006) Sorption of Fe(II) and As(III) on goethite in single- and dual-sorbate systems. Chem. Geol |  | Verron, Héloïse, Sterpenich, Jérôme, Bonnet, Julien, Bourdelle, Franck, Mosser-Ruck, Régine, Lorgeoux, Catherine, Randi, Aurélien, Michau, Nicolas (2019) Experimental Study of Pyrite Oxidation at 100 °C: Implications for Deep Geological Radwaste Repository in Claystone. Minerals, 9 (7) 427 doi:10.3390/min9070427 | Journal (article/letter/editorial) | | where the underground laboratory of Andra was built (Bure, Meuse, France). This claystone is a part of Minerals...484 L. The phases authorized to precipitate were goethite, hematite, magnetite, amorphous magnetite, melanterite...484 L. The phases authorized to precipitate were goethite, hematite, magnetite, amorphous magnetite, melanterite |  | | Journal (issue) | | G 15 - Yugoslavia. G 16 - Belgiq ue. G 17 - Luxembourg . G 181 - France : Massif Central (5 excursions)...Chai l lac, Les Farges, Pessens, Lacan, Mont-Roc, Bure, les Corbières, le Boulou , Escaro et Sahorre)....Escaro et Sahorre , Salsigne, St-Salvy, Mont-Roc, Bure, Montredon-Labessonnie). LE LIVRET-GUIDE DES EXCURSIONS...l'améthyste : bixbyite, calcite, hématite, limonite, goethite et, assez rarement, de la vivianite. L'accès à...pharmacosidérite. St-Austell Fer, cuivre, galène, goethite, étain, sulfures de bismuth et cuivre, St-Just |  | | Journal (article/letter/editorial) | | Châtenay-Malabry, France (scott.altmann@andra.fr) 2 Andra URL, Bure, France Long-term measurements (up to ~ 6 years)...Callovo-Oxfordien (C-O) formation at the Andra URL (Bure, eastern France) show trends towards apparently...UO22+ sorption onto goethite and nontronite Adsorption of Lanthanum to goethite in the presence of gluconic...important constituents of radioactive wastes. Goethite and the clay mineral, nontronite, could form during...is found that adsorption of Gd3+ and U(VI) onto goethite and nontronite increases in the range of pH from |  | Marshall-Bowman, Karina, Ohara, Shohei, Sverjensky, Dimitri A., Hazen, Robert M., Cleaves, H. James (2010) Catalytic peptide hydrolysis by mineral surface: Implications for prebiotic chemistry. Geochimica et Cosmochimica Acta, 74 (20) 5852-5861 doi:10.1016/j.gca.2010.07.009 | Journal (article/letter/editorial) | | Physical Basis of Life. Routledge, London. Bertrand M., Bure C., Fleury F. and Brack A. (2001) Prebiotic polymerisation...fractionation upon adsorption of fulvic acid on goethite: equilibrium and kinetic studies. Geochim. Cosmochim |  | | Book (volume) | | and the following national chapters: France and Luxembourg by J. Bouladon Spain by F. Vazquez Guzman Portugal...Switzerland, Czechoslovakia, the Netherlands and Belgium; Southeast Europe includes Albania, Bulgaria, Cyprus...sedimentary basins Conclusions 30 31 France and Luxembourg by J. Bouladon Introduction 37 37 I I 4 5...of zone D Paris Basin (including Lorraine and Luxembourg) and Aquitaine Basin (zone E) Iron. Sulphur Gypsum...introduction, comprises the territories of France, Luxembourg, Italy, Spain and Portugal. It covers an area |
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